Kurskii, Yu. A.; Baryshnikov, Yu. N.; Kaloshina, N. N.; Vesnovskaya, G. I.
J. Gen. Chem. USSR (Engl. Transl.), 1981 , vol. 51, # 2 p. 362 - 366,293 - 296
Kurskii, Yu. A.; Baryshnikov, Yu. N.; Kaloshina, N. N.; Vesnovskaya, G. I.
J. Gen. Chem. USSR (Engl. Transl.), 1981 , vol. 51, # 2 p. 362 - 366,293 - 296
Kurskii, Yu. A.; Baryshnikov, Yu. N.; Kaloshina, N. N.; Vesnovskaya, G. I.
J. Gen. Chem. USSR (Engl. Transl.), 1981 , vol. 51, # 2 p. 362 - 366,293 - 296
Kurskii, Yu. A.; Baryshnikov, Yu. N.; Kaloshina, N. N.; Vesnovskaya, G. I.
J. Gen. Chem. USSR (Engl. Transl.), 1981 , vol. 51, # 2 p. 362 - 366,293 - 296
in n-heptane T=-20°C; addition of lithium tert- butoxide or lithium trimethylsilanolate; KineticsMechanism;
参考文献
Baryshnikov, Yu. N.; Kurskii, Yu. A.; Kaloshina, N. N.; Vesnovskaya, G. I.
J. Gen. Chem. USSR (Engl. Transl.), 1982 , vol. 52, # 10 p. 2288 - 2292,2037 - 2040
Kurskii, Yu. A.; Baryshnikov, Yu. N.; Kaloshina, N. N.; Vesnovskaya, G. I.
J. Gen. Chem. USSR (Engl. Transl.), 1981 , vol. 51, # 2 p. 362 - 366,293 - 296
1: in diethyl ether; hexane T=-78°C; 2: With chloro-trimethyl-silane in diethyl ether; hexane T=-78 - 0°C; 3: With zinc in methanol; diethyl ether; hexane T=0°C; Clemmensen Reduction; 1 h;
参考文献
Organic Letters, , vol. 15, # 17 p. 4327 - 4329
→
反应条件
1: 2',2'-dibromocycloprop-1'-yloxirane; n-butyllithium in diethyl ether; hexane T=-75 - 20°C; 2.5 h; 2: p-toluenesulfonyl chloride With sodium hydride in tetrahydrofuran T=-15°C; 2 h; Title compound not separated from byproducts;
参考文献
Bentley, T. William; Engels, Bernd; Hupp, Thomas; Bogdan, Elena; Christl, Manfred
Journal of Organic Chemistry, 2006 , vol. 71, # 3 p. 1018 - 1026
