tert.-butylhydroperoxide; molecular sieve in tert-butyl alcohol T=60°C; 40 h; other metal substituted octahedral molecular sieves as catalysts; var. temp. and time, effect of tert-butyl hydrogen peroxide, catalyst and solvent amounts; Product distribution;
参考文献
Wang, Jin-Yun; Xia, Guan-Guang; Yin, Yuan-Gen; Suib, Steven L.; O'Young
Journal of Catalysis, 1998 , vol. 176, # 2 p. 275 - 284
hydrogen sulfide; oxygen; iron in pyridine; acetic acid Ambient temperatureiron catalyzed insertion of sulfur into the non-activated C-H bond; variation of the sulfur reagent, the catalyst and of the AcOH conc.; or in CF3COOH; or with other cyclic hydrocarbons; Product distributionMechanismKinetics;
CoAPO-5; oxygen; acetaldehyde in acetic acid T=109.9°C; P=15751.3 Torr; role of cobalt molecular sieves;
参考文献
Belkhir, Ines; Germain, Alain; Fajula, Francois; Fache, Eric
Journal of the Chemical Society - Faraday Transactions, 1998 , vol. 94, # 12 p. 1761 - 1764
