Cu2Cl2; ethylmagnesium bromide; n-octylmagnesium bromide in diethyl ether T=-20°C; 1.) 20 min, 2.) 1.5 h; Further byproducts given. Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 54, # 8 p. 1948 - 1951
in hexane; cyclohexane to 1-bromooctane (1 mmol) and Bu3SnH (1 mmol) in hexane at 0°C added LDA (1 mmol, in cyclohexane) under Ar, stirred for 20 min, quenched; analyzed by GLPC;
