potassium methanolate in methanol T=40°C; electrolysis: anode: platinum foil; current source: galvanostat; current density 200 mA cm-2; current consumption: 3.03 F mol-1; cell voltage 50-60 V; Yield given;
1: With tri-isobutyl aluminium; bis-triphenylphosphine-palladium(II) chloride in dichloromethane T=25°C; 12 h; 2: With sodium hydroxide; oxygen in dichloromethane
sodium (tert-butylamino)trihydroborate in tetrahydrofuran T=66°C; 96 h; further reducing agent: sodium (dimethylamino)trihydroborat (NaDMAB); Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 49, # 13 p. 2438 - 2443
