2-甲基-2-环己烯-1-酮合成路线 （共 131 条）
反应条件
dihydrogen peroxide in water; acetonitrile
T=50°C; 2 h;
参考文献
Armatas, Gerasimos S.; Bilis, Georgios; Louloudi, Maria
Journal of Materials Chemistry, 2011 , vol. 21, # 9 p. 2997 - 3005
反应条件
1: With N-bromosuccinmide in tetrachloromethane
4 h; Heating;
2: With lithium carbonate; lithium bromide in N,N-dimethyl-formamide
参考文献
Baker, Lucas; Minehan, Thomas
Journal of Organic Chemistry, 2004 , vol. 69, # 11 p. 3957 - 3960
反应条件
1H-imidazole; dihydrogen peroxide; acetic anhydride in ethanol
T=30°C; 0.5 h; SonicationGreen chemistry;
参考文献
Rayati, Saeed; Bohloulbandi, Elaheh
Comptes Rendus Chimie, 2014 , vol. 17, # 1 p. 62 - 68
反应条件
trifluoroacetic acid; bis-[(trifluoroacetoxy)iodo]benzene in water; acetonitrile
1.5 h; Heating;
参考文献
Moriarty; Berglund; Penmasta
Tetrahedron Letters, 1992 , vol. 33, # 41 p. 6065 - 6068
反应条件
1-methyl-pyrrolidin-2-one; iron (III) acetylacetonate in tetrahydrofuran
T=15 - 20°C; 0.25 h;
参考文献
Cahiez, Gerard; Avedissian, Hovsep
Synthesis, 1998 , # 8 p. 1199 - 1205
反应条件
iron(III) chloride in methanol
T=60°C;
参考文献
Ito, Satoru; Aihara, Kazuhisa; Matsumoto, Masakatsu
Tetrahedron Letters, 1984 , vol. 25, # 35 p. 3891 - 3894
反应条件
sulfuric acid; paraformaldehyde in water
参考文献
International Flavors and Fragrances Inc.
Patent: US4794193 A1, 1988 ;
反应条件
1: 87 percent / ammonium formate / PdCl2(PPh3)2 / dioxane / Heating
2: 67 percent / t-AmONa / 1,2-dimethoxy-ethane / 25 °C
3: 95 percent / Pd(OAc)2, 1,2-bis(diphenylphosphino)ethane / acetonitrile / 0.5 h / Heating
View Scheme
参考文献
Shimizu, Isao; Tsuji, Jiro
Journal of the American Chemical Society, 1982 , vol. 104, # 21 p. 5844 - 5846
反应条件
carbon dioxide; oxygen; 1-hydroxy-pyrrolidine-2,5-dione; anhydrous cobalt diacetate
T=60 - 100°C; P=44734.5 Torr; 6 h; Product distribution / selectivity;
参考文献
University of Kansas
Patent: US2008/139841 A1, 2008 ;
Location in patent: Page/Page column 8 ;
参考文献
ALLERGAN SALES, INC.
Patent: US2002/161051 A1, 2002 ;
