119072-55-8合成路线 （共 225 条）
反应条件
acetic acid; sodium nitrite in water; acetonitrile
T=0 - 20°C; 3 h; Inert atmosphere;
参考文献
Basavanag, Unnamatla M. V.; Dos Santos, Aurelie; El Kaim, Laurent; Gamez-Montano, Rocio; Grimaud, Laurence
Angewandte Chemie - International Edition, 2013 , vol. 52, # 28 p. 7194 - 7197
Angew. Chem., 2013 , vol. 125, # 28 p. 7335 - 7338,4
反应条件
1: tert-butylisonitrile; diphenyl acetylene With Ti(dpm)(NMe2)2; aniline in toluene
T=125°C; 48 h; Inert atmosphere;
2: benzenecarboximidamide hydrochloride in 1,1-dimethylpropan-1-ol
T=150°C; 24 h; Inert atmosphere;
参考文献
Majumder, Supriyo; Odom, Aaron L.
Tetrahedron, 2010 , vol. 66, # 17 p. 3152 - 3158
反应条件
1,1'-bis-(diphenylphosphino)ferrocene; caesium carbonate; palladium dichloride in toluene
2 h; RefluxInert atmosphere;
参考文献
Bochatay, Valentin N.; Boissarie, Patrick J.; Murphy, John A.; Suckling, Colin J.; Lang, Stuart
Journal of Organic Chemistry, 2013 , vol. 78, # 4 p. 1471 - 1477
反应条件
hydrogen in dichloromethane
dry solvents; degassing isonitrile and Mo-compd. dissolved in CH2Cl2, placing under hydrogen (375-400 Torr), stirring at ambient temperature (3 days); removal of solvent, extn. (toluene), filtration, shaking residue (Et2O/Na2CO3), filtration, extn. residue (MeCN), filtration, crystn. by addn. of Et2O, filtration, drying in vac.; (CpMo)2(S2CH2)2 and ((CpMo)2S4C6H12N)CF3SO3 not isolated, detn. (1)H-NMR;
参考文献
Bernatis, Paul; Laurie, J. C. V.; Rakowski DuBoi, M.
Organometallics, 1990 , vol. 9, p. 1607 - 1617
反应条件
1: pyridine-2-carbaldehyde; ethylenediamine in methanol
T=45 - 50°C; 3 h;
2: tert-butylisonitrile With chloro-trimethyl-silane in methanol; acetonitrile
T=20 - 60°C;
参考文献
Kysil, Volodymyr; Khvat, Alexander; Tsirulnikov, Sergey; Tkachenko, Sergey; Williams, Caroline; Churakova, Marina; Ivachtchenko, Alexandre
European Journal of Organic Chemistry, 2010 , # 8 p. 1525 - 1543
反应条件
1: pyridine-4-carbaldehyde; ethylenediamine in methanol
T=45 - 50°C; 3 h;
2: tert-butylisonitrile With chloro-trimethyl-silane in methanol; acetonitrile
T=20 - 60°C;
参考文献
Kysil, Volodymyr; Khvat, Alexander; Tsirulnikov, Sergey; Tkachenko, Sergey; Williams, Caroline; Churakova, Marina; Ivachtchenko, Alexandre
European Journal of Organic Chemistry, 2010 , # 8 p. 1525 - 1543
反应条件
iodine; oxygen; sodium carbonate; palladium diacetate in acetonitrile
T=100°C; P=2068.6 Torr; 3 h;
参考文献
Pri-Bar, Ilan; Schwartz, Jeffrey
Chemical Communications, 1997 , # 4 p. 347 - 348
反应条件
1: tert-butylisonitrile; 2-amino-benzenethiol in N,N-dimethyl-formamide
T=120°C; 24 h; Inert atmosphere;
2: 3-bromo-pyridine With 1,1'-bis-(diphenylphosphino)ferrocene; copper(l) iodide; palladium diacetate; caesium carbonate in N,N-dimethyl-formamide
T=120°C; 24 h; Inert atmosphere;
参考文献
Bochatay, Valentin N.; Boissarie, Patrick J.; Murphy, John A.; Suckling, Colin J.; Lang, Stuart
Journal of Organic Chemistry, 2013 , vol. 78, # 4 p. 1471 - 1477
反应条件
1: pyridine With fluorine in chloroform
T=-78 - -60°C;
2: tert-butylisonitrile With trimethylsilylazide in chloroform
T=-50 - 0°C;
参考文献
Kiselyov, Alexander S.
Tetrahedron Letters, 2005 , vol. 46, # 29 p. 4851 - 4854
反应条件
2,2'-azo-bisisobutyronitrile; tris-(trimethylsilyl)silane in toluene
T=90°C; 0.5 h;
参考文献
Chatgilialoglu; Giese; Kopping
Tetrahedron Letters, 1990 , vol. 31, # 42 p. 6013 - 6016
