3-甲基-2-环己烯-1-酮合成路线 （共 314 条）
参考文献
Skita; Ritter
Chemische Berichte, 1911 , vol. 44, p. 673
反应条件
Behandeln mit Zinkstaub;
参考文献
Knoevenagel
Justus Liebigs Annalen der Chemie, 1897 , vol. 297, p. 183
反应条件
1: diethyl ether 2: (i) aq. HClO4, Et2O, (ii) /BRN= 878250/, (iii) aq. NaOH, EtOH View Scheme
参考文献
Mirrington,R.N.; Schmalzl,K.J.
Journal of Organic Chemistry, 1969 , vol. 34, # 8 p. 2358 - 2363
反应条件
in diethyl ether T=-78°C; Addition;
参考文献
Arai, Noriyoshi; Narasaka, Koichi
Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 10 p. 2525 - 2534
反应条件
in diethyl ether 4 h; Heating;
参考文献
Eilbracht, Peter; Jelitte, Ruediger; Trabold, Peter
Chemische Berichte, 1986 , vol. 119, # 1 p. 169 - 181
参考文献
Mirrington,R.N.; Schmalzl,K.J.
Journal of Organic Chemistry, 1969 , vol. 34, # 8 p. 2358 - 2363
反应条件
diethyl ether; methylmagnesium bromide
参考文献
Braude et al.
Journal of the Chemical Society, 1956 , p. 4054,4058
参考文献
v. Auwers
Chemische Berichte, 1913 , vol. 46, p. 2995
反应条件
1: methylmagnesium bromide With copper (I) cyanide T=0°C; 0.5 h; 2: 3-methyl-cyclohex-2-en-1-one in diethyl ether T=-78 - -20°C; 2 h; 3: With ammonium chloride in diethyl ether; water pH=7.2; Aqueous phosphate buffer;
参考文献
ALMIRALL PRODESFARMA, S.A.
Patent: WO2007/17078 A1, 2007 ;
Location in patent: Page/Page column 23-24 ;
反应条件
1: methylmagnesium bromide With copper (I) cyanide T=0°C; 0.5 h; 2: 3-methyl-cyclohex-2-en-1-one in diethyl ether T=-78 - -20°C; 2 h; 3: With water pH=7.2; Phosphate buffer;
参考文献
ALMIRALL PRODESFARMA, S.A.
Patent: WO2006/58724 A1, 2006 ;
Location in patent: Page/Page column 34 ;
