(1,5-环辛二烯)二氯化钯(II)合成路线 （共 29 条）
反应条件
in dichloromethane Schlenk techniques, under N2 or Ar; according to P. Gugger, S.O. Limmer,A.A. Watson, A.C. Willis, S.B. Wild, Inorg. Chem. 32 (1993) 5692; phosp hine ligand reacted with equimolar amt. of Pd complex;
参考文献
Luo, He-Kuan; Yang, Hai-Yan; Jie, Tan Xiang; Chiew, Ong Siong; Schumann, Herbert; Khim, Lim Bee; Lim, Christina
Journal of Molecular Catalysis A: Chemical, 2007 , vol. 261, # 1 p. 112 - 119
反应条件
in dichloromethane (N2); dropwise addn. of the Pd-complex to the Rh-complex in CH2Cl2, stirring for 1 h; the volume of the soln. is reduced, addn. of diethyl ether, filtration, washing (diethyl ether), drying in vac., elem. anal.;
参考文献
Inorganic Chemistry, , vol. 31, p. 4797 - 4802
反应条件
in methanol under N2; Pd complex reacted with 4 equivs. of phosphorus ligand; product washed with Et2O and dried in vacuo; elem. anal.;
参考文献
Trzeciak; Bartosz-Bechowski; Ciunik; Niesyty; Ziolkowski
Canadian Journal of Chemistry, 2001 , vol. 79, # 5-6 p. 752 - 759
反应条件
in dichloromethane under N2, addn. of complex in CH2Cl2 to soln. of ligand in CH2Cl2, stirred for 25°C for 2 h, white pptn.; evapd. under reduced press., addn. of toluene, heated under reflux for 4 h, yellow pptn., filtered, dried in vac.;
参考文献
Polyhedron, , vol. 12, p. 721 - 730
反应条件
in dichloromethane under N2, addn. of complex in CH2Cl2 to soln. of ligand in CH2Cl2, stirred for 25°C for 2 h, white pptn.; evapd. under reduced press., addn. of toluene, heated under reflux for 4 h, pptn., filtered, dried in vac.;
参考文献
Broadwood-Strong, Gillian T. L.; Chaloner, Penny A.; Hitchcock, Peter B.
Polyhedron, 1993 , vol. 12, p. 721 - 730
反应条件
in not given under N2; Pd complex reacted with 2 equivs. of phosphorus ligand; product washed with Et2O and dried in vacuo; elem. anal.;
参考文献
Canadian Journal of Chemistry, , vol. 79, # 5-6 p. 752 - 759
反应条件
in dichloromethane
byproducts: Me3SiX; N2-atmosphere; 2 equivs. of Pd-complex, 10 h; not sepd.; NMR spectroscopy (quantitative yield);
参考文献
Steenwinkel, Pablo; Jastrzebski, Johann T. B. H.; Deelman, Berth-Jan; Grove, David M.; Kooijman, Huub; Veldman, Nora; Smeets, Wilberth J. J.; Spek, Anthony L.; Van Koten, Gerard
Organometallics, 1997 , vol. 16, # 25 p. 5486 - 5498
反应条件
in dichloromethane
byproducts: Me3SnX; N2-atmosphere; 2 equivs. of Pd-complex; not sepd.; NMR spectroscopy (quantitative yield);
参考文献
Steenwinkel, Pablo; Jastrzebski, Johann T. B. H.; Deelman, Berth-Jan; Grove, David M.; Kooijman, Huub; Veldman, Nora; Smeets, Wilberth J. J.; Spek, Anthony L.; Van Koten, Gerard
Organometallics, 1997 , vol. 16, # 25 p. 5486 - 5498
反应条件
in dichloromethane
(N2); addn. of CH2Cl2 soln. of palladium compd. to CH2Cl2 soln. of phosphine deriv., stirring at room temp. for 4 h; evapn., washing with pentane, drying in vac. for 1 d;
参考文献
Arumugam, Kuppuswamy; Shaw, Mohamed C.; Chandrasekaran; Villagran, Dino; Gray, Thomas G.; Maguey, Joel T.; Donahue, James P.
Inorganic Chemistry, 2009 , vol. 48, # 22 p. 10591 - 10607
