双(1,5-环辛二烯)镍(0)合成路线 （共 74 条）
反应条件
in hexane under Ar Fe-complex was suspended in hexane at 0°C, Ni-complex was added, stirred at 0°C for 45 min; filtered, evapd., detected by IR;
参考文献
VanDerveer, Michael C.; Burlitch, James M.
Journal of Organometallic Chemistry, 1980 , vol. 197, # 3 p. 357 - 368
反应条件
triphenylphosphine in tetrahydrofuran under N2 or argon or under vac., soln. of org. compd. (3.8 mol) added to mixt. of Ni(cod)2 and PPh3 (1.0/2.2 mol ratio), stirred at 30°Cfor 2 d; detn. by IR and NMR;
参考文献
Journal of the American Chemical Society, , vol. 103, # 23 p. 6863 - 6869
反应条件
in toluene under Ar, Ni(COD)2 and Ph2PCH2COOH dissolved in toluene, kept 1 h at room temp., solvent distilled off at E-2 Torr, residue dissolved in mixt. of toluene and n-hexene, cooled to -30°C, filtered off, added n-hexane and n-octane, kept several d; recrystd. from mixt. of toluene, hexane, and octane;
参考文献
Peuckert, Marcell; Keim, Wilhelm
Organometallics, 1983 , vol. 2, p. 594 - 597
反应条件
triphenylphosphine in benzene (Ar); PPh3 (2 equiv) soln. added to complex and vinyltrimethylsilane mixt. in C6H6 at 22°C, stirred for 18 h; evapd., dissolved in ether, treated with pentane, ppt. filtered off, washed with pentane, dried (vac.); elem. anal.;
参考文献
Isaeva, L. S.; Peganova, T. A.; Petrovskii, P. V.; Kayumov, F. F.; Yusupova, F. G.; Yur'ev, V. P.
Journal of Organometallic Chemistry, 1983 , vol. 248, # 3 p. 375 - 381
反应条件
sodium amalgam in tetrahydrofuran N2 or Ar-atmosphere; stirring (16 h); centrifugation, evapn. (vac.); detd. by (31)P NMR spectroscopy;
参考文献
Bennett, Martin A.; Johnson, Julian A.; Willis, Anthony C.
Organometallics, 1996 , vol. 15, # 1 p. 68 - 74
反应条件
P(C6H5)3 in pentane addn. of Ti-compd. and PPh3 to a soln. of Ni-compd., spect. detection of intermediate, extn. of intermediate into pentane, standing at 20°C for 4 days; decantation of crystals;
参考文献
Dick, David G.; Stephan, Douglas W.; Campana, Charles F.
Canadian Journal of Chemistry, 1990 , vol. 68, # 4 p. 628 - 632
反应条件
hydrogen in hexane 1 atm., 20°C, vigorous reaction after induction period;
参考文献
Bogdanovic,B. et al.
Justus Liebigs Annalen der Chemie, 1966 , vol. 699, p. 1 - 23
反应条件
in tetrahydrofuran byproducts: H2; under Ar, stirring for 20 h; filtration of ppt., drying in vac., dissolving in hot CHCl3 and pptn. by. addn. of Et2O; elem. anal.;
参考文献
Zeitschrift fuer Anorganische und Allgemeine Chemie, , vol. 566, p. 121 - 130
反应条件
P(C6H5)3 in toluene N2-atmosphere; equimolar amts., 220-240 K; product mixt. not sepd., detd. by (31)P-NMR spectroscopy;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , # 21 p. 3075 - 3084
反应条件
triphenylphosphine in diethyl ether ethereal susp., cooling with ice;
参考文献
Bogdanovic,B. et al.
Justus Liebigs Annalen der Chemie, 1966 , vol. 699, p. 1 - 23
