双(1,5-环辛二烯)镍(0)合成路线 （共 74 条）
反应条件
in hexane
molar ratio Ni(C8H12)2 : t-C4H9NC = 1 : 10;
参考文献
Nast, R.; Schulz, H.; Moerler, H.-D.
Chemische Berichte, 1970 , vol. 103, p. 777 - 784
Full Text Show Details
Gmelin Handbook: Ni: Org.Verb.1, 1.1.6.4.1, page 327 - 333
反应条件
in toluene
T=20°C; 4 h; Inert atmosphere;
参考文献
Doster, Meghan E.; Johnson, Samuel A.
Organometallics, 2013 , vol. 32, # 15 p. 4174 - 4184
反应条件
in toluene
all manipulations under Ar atm.; soln. of isocyanide added to soln. of Ni compd. over period of 1 h at room temp.; concd., cooled to -10°C, after 24 h filtered; elem. anal.;
参考文献
Hahn, F. Ekkehardt; Muender, Marco; Froehlich, Roland
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2004 , vol. 59, # 8 p. 850 - 854
反应条件
carbon monoxide in hexane
-40°C, warming within 1 h to 0-20°C;
参考文献
Bogdanovic,B. et al.
Justus Liebigs Annalen der Chemie, 1966 , vol. 699, p. 1 - 23
反应条件
CO in tetrahydrofuran
under CO a soln. of Ti-complex and Ni-complex in THF was stirred;
参考文献
VanDerveer, Michael C.; Burlitch, James M.
Journal of Organometallic Chemistry, 1980 , vol. 197, # 3 p. 357 - 368
参考文献
Gmelin Handbook: Ni: Org.Verb.1, 1.1.5.4.1.1.3, page 202 - 205
反应条件
in hexane
under Ar Fe-complex was suspended in hexane at 0°C, Ni-complex was added, stirred at 0°C for 45 min; filtered, evapd., detected by IR;
参考文献
VanDerveer, Michael C.; Burlitch, James M.
Journal of Organometallic Chemistry, 1980 , vol. 197, # 3 p. 357 - 368
反应条件
in diethyl ether
between -50°C and boiling temp.;
参考文献
Tolman,C.A.
Journal of the American Chemical Society, 1970 , vol. 92, p. 2956 - 2965
Full Text View citing articles Show Details
Gmelin Handbook: Ni: Org.Verb.2, 1.4.2.1.1.3, page 89 - 93
反应条件
in pentane
byproducts: 1,5-cyclooctadiene; (N2); mixed (-78°C), stirred, warmed to -20°C; filtered (-20°C), cooled (-78°C), ppt. washed (cold pentane), dried (vac.); Ni(PMe3)4 sublimited (40°C, 0.1 Torr); NMR, elem. anal.;
参考文献
Karsch, Hans Heinz; Appelt, Armin
Journal of Organometallic Chemistry, 1986 , vol. 314, p. C5 - C8
参考文献
Gmelin Handbook: Ni: Org.Verb.2, 1.4.2.1.1.3, page 89 - 93
