双(1,5-环辛二烯)镍(0)合成路线 （共 74 条）
反应条件
in neat (no solvent)
mixt. sealed under Ar in quartz tube at -80 °C, heated to 650 °C for 2 h; product ground in the powder, washed (conc. HCl), dispersed in 2-propanol, sonicated for 1 min; detd. by TEM;
参考文献
Iyer, Vivekanantan S.; Vollhardt, K. Peter C.; Wilhelm, Rene
Angewandte Chemie - International Edition, 2003 , vol. 42, # 36 p. 4379 - 4383
反应条件
1-hexene in further solvent(s)
byproducts: 2-hexene, 3-hexene; under N2; in NMR tube; soln. of Ni(COD)2 in hexene-1 and C6D6 mixed withsoln. of Ni-PPh3 complex in C6D6; not isolated; monitored by (1)H, (31)P and (19)F NMR spectra;
参考文献
Stapleton, Russell L.; Chai, Jianfang; Taylor, Nicholas J.; Collins, Scott
Organometallics, 2006 , vol. 25, # 10 p. 2514 - 2524
反应条件
in diethyl ether
Ni-complex was treated with In-complex in ether at -80°C, warmed to -10°C;
参考文献
Green, Shaun P.; Jones, Cameron; Stasch, Andreas
Inorganic Chemistry, 2007 , vol. 46, # 1 p. 11 - 13
参考文献
Gmelin Handbook: Ni: Org.Verb.2, 1.4.2.1.1.3, page 89 - 93
