2-氯-9H-氧杂蒽-9-酮合成路线 （共 18 条）
参考文献
Mustafa et al.
Journal of the American Chemical Society, 1955 , vol. 77, p. 5121,5123
参考文献
Mustafa et al.
Journal of the American Chemical Society, 1955 , vol. 77, p. 5121,5123
反应条件
potassium carbonate in acetone
T=50°C; 2 h;
参考文献
Zhou, Chengxiang; Larock, Richard C.
Journal of Organic Chemistry, 2006 , vol. 71, # 9 p. 3551 - 3558
反应条件
tert.-butylhydroperoxide; Rhodium trichloride; triphenylphosphine in chlorobenzene
T=160°C; 24 h; Inert atmosphere;
参考文献
Wang, Ping; Rao, Honghua; Hua, Ruimao; Li, Chao-Jun
Organic Letters, 2012 , vol. 14, # 3 p. 902 - 905
反应条件
1: K2CO3 / N,N-dimethyl-acetamide / 2 h / 170 °C
2: MgSO4 / toluene / 100 °C
3: cesium pivalate / Pd(OAc)2; 1,1-bis(diphenylphosphino)methane / dimethylformamide / 24 h / 100 °C
4: aq.HCl / acetone
View Scheme
参考文献
Zhao, Jian; Yue, Dawei; Campo, Marino A.; Larock, Richard C.
Journal of the American Chemical Society, 2007 , vol. 129, # 16 p. 5288 - 5295
反应条件
1: K2CO3 / N,N-dimethyl-acetamide / 2 h / 170 °C
2: MgSO4 / toluene / 100 °C
3: cesium pivalate / Pd(OAc)2; 1,1-bis(diphenylphosphino)methane / dimethylformamide / 24 h / 100 °C
4: aq.HCl / acetone
View Scheme
参考文献
Zhao, Jian; Yue, Dawei; Campo, Marino A.; Larock, Richard C.
Journal of the American Chemical Society, 2007 , vol. 129, # 16 p. 5288 - 5295
反应条件
cesium fluoride in acetonitrile
T=20°C; 15 h;
参考文献
Okuma, Kentaro; Nojima, Akiko; Matsunaga, Nahoko; Shioji, Kosei
Organic Letters, 2009 , vol. 11, # 1 p. 169 - 171
反应条件
potassium phosphate; triphenylphosphine; copper dichloride in toluene
T=110°C; 24 h;
参考文献
Hu, Jun; Adogla, Enoch A.; Ju, Yong; Fan, Daping; Wang, Qian
Chemical Communications, 2012 , vol. 48, # 91 p. 11256 - 11258
反应条件
1.1: TFA; DMSO / Pd(OAc)2 / 24 h / Heating
1.2: 42 percent / H2O / 2 h / 70 °C
2.1: 98 percent / K2CO3 / acetone / 2 h / 50 °C
View Scheme
参考文献
Zhou, Chengxiang; Larock, Richard C.
Journal of Organic Chemistry, 2006 , vol. 71, # 9 p. 3551 - 3558
反应条件
sulfuric acid
1 h; Heating;
参考文献
Pellon; Carrasco; Milian; Rodes
Synthetic Communications, 1995 , vol. 25, # 7 p. 1077 - 1083
