2,5-二甲基-3-己炔-2,5-二醇合成路线 （共 93 条）
反应条件
bei der katalytischen Hydrierung entstehen je nach den Bedingungen verschiedene Produkte.Hydrogenation;
参考文献
Dupont
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1913 , vol. 156, p. 1624
Annales de Chimie (Cachan, France), 1913 , vol. <8>30, p. 516
反应条件
sodium hydroxide T=40 - 45°C;
参考文献
Chatt,J. et al.
Journal of the Chemical Society, 1963 , p. 5170 - 5183
参考文献
Salkind; Chasowa
Zhurnal Obshchei Khimii, 1948 , vol. 18, p. 2136,2139
Chem.Abstr., 1949 , p. 3782
Full Text Show Details
Mamedow
Chem.Abstr., 1943 , p. 1699
参考文献
Salkind; Chasowa
Zhurnal Obshchei Khimii, 1948 , vol. 18, p. 2136,2139
Chem.Abstr., 1949 , p. 3782
反应条件
1: 100 percent / hydrogen / Pd/CaCO3 / quinoline 2: 75 percent / diethylamine / 4-Dimethylamino pyridine / CH2Cl2 / 3 h 3: 80 percent / Tetrakis (triphenylphosphine) palladium / 15 h / 60 °C 4: 1.) decarbomethoxylation 5: Lithium diisopropylamide / tetrahydrofuran / 4.5 h / -78 - 25 °C / pruduct ratio cis and trans = 3:2 6: H2O / hydrolisis and isomerization View Scheme
参考文献
Genet, J.P.; Piau, F.; Ficini, J.
Tetrahedron Letters, 1980 , vol. 21, p. 3183 - 3186
反应条件
dihydrogen peroxide; copper(II) sulfate T=60 - 80°C;
参考文献
Res.Corp.New York
Patent: US2347358 , 1942 ;
反应条件
T=60 - 80°C; Produkt5: CO2;
参考文献
Lwow; Akopjan; Poljuta
Zhurnal Obshchei Khimii, 1941 , vol. 11, p. 300,301
Chem.Abstr., 1941 , p. 5858
Chem. Zentralbl., 1942 , vol. 113, # I p. 1122
反应条件
T=60 - 80°C; Produkt5: CO2;
参考文献
Lwow; Akopjan; Poljuta
Zhurnal Obshchei Khimii, 1941 , vol. 11, p. 300,301
Chem.Abstr., 1941 , p. 5858
Chem. Zentralbl., 1942 , vol. 113, # I p. 1122
参考文献
Dupont
Annales de Chimie (Cachan, France), 1913 , vol. <8> 30, p. 539,583
反应条件
methanol; sulfuric acid T=60 - 65°C;
参考文献
Dupont
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1911 , vol. 152, p. 198
Annales de Chimie (Cachan, France), 1913 , vol. <8>30, p. 512
