1,1-二甲基-2,5-二氢硅杂环戊二烯合成路线 （共 40 条）
反应条件
1: Rose Bengal / methanol / 1.5 h / Irradiation 2: aq. NaBH4 / methanol / 12 h 3: d'alumine activee en grains / 290 °C / 0.01 Torr View Scheme
参考文献
Laporterie, Andre; Dubac, Jacques; Mazerolles, Pierre; Iloughmane, Hafida
Journal of Organometallic Chemistry, 1981 , vol. 216, # 3 p. 321 - 329
反应条件
hydrogen; Wilkinson's catalyst T=45 - 80°C; Yield given;
参考文献
Journal of Organometallic Chemistry, , vol. 284, p. 5 - 12
反应条件
buta-1,3-diene T=550°C; half-reaction time; Rate constant;
参考文献
Chernyshev, E. A.; Bykovchenko, V. G.; Komalenkova, N. G.; Kel'man, M. Ya.; Kisileva, T. S.; Shevchenko, O. V.
J. Gen. Chem. USSR (Engl. Transl.), 1991 , vol. 61, # 1.2 p. 162 - 165,143 - 146
反应条件
potassium-sodium in gaseous matrix
T=280 - 320°C; P=0.1 - 1 Torr;
参考文献
Gusel'nikov, L. E.; Polyakov, Yu. P.; Volnina, E. A.; Nametkin, N. S.
Journal of Organometallic Chemistry, 1985 , vol. 292, p. 189 - 204
反应条件
silica immobilized second generation Hoveyda-Grubbs catalyst in hexane
T=44.84°C; 4 h;
参考文献
Van Berlo, Boris; Houthoofd, Kristof; Sels, Bert F.; Jacobs, Pierre A.
Advanced Synthesis and Catalysis, 2008 , vol. 350, # 13 p. 1949 - 1953
反应条件
tetrabutylstannane; aluminum oxide; Re2O7 in n-heptane
T=45°C; 3 h;
参考文献
Finkel'shtein, E. Sh.; Portnykh, E. B.; Ushakov, N. V.; Vdovin, V. M.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1981 , vol. 30, # 3 p. 483 - 487
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1981 , # 3 p. 641 - 645
反应条件
titanocene dichloride in tetrahydrofuran
T=-40°C; 4 h;
参考文献
Matthews, Jennifer L; McArthur, Duncan R; Muir, Kenneth W
Tetrahedron Letters, 2002 , vol. 43, # 31 p. 5401 - 5404
参考文献
Bain,S.; Ijadi-Maghsoodi,S.; Barton,T.J.
Journal of the American Chemical Society, 1988 , vol. 110, p. 2611
反应条件
T=600°C; Further byproducts given;
参考文献
Conlin,R.T.; Huffaker,H.B.; Kwak,Y.W.
Journal of the American Chemical Society, 1985 , vol. 107, p. 731
反应条件
in toluene
1.) 4 h, 0 deg C, 2.) 14 h, room temp.;
参考文献
Richter, Wolf Juergen
Synthesis, 1982 , # 12 p. 1102
