顺 -1,2-环己二醇合成路线 (共 184 条)
反应条件
dihydrogen peroxide; [Fe(II)(5-Me3-tris(2-pyridylmethyl)amine)(CH3CN)2](ClO4)2 in acetonitrile T=4°C; Title compound not separated from byproducts.;
参考文献
Chemical communications (Cambridge, England), , # 12 p. 1288 - 1289
反应条件
[FeII(Ph-DPAH)2](OTf)2; dihydrogen peroxide in acetonitrile T=25°C; 1 h; Title compound not separated from byproducts;
参考文献
Journal of the American Chemical Society, , vol. 127, # 45 p. 15672 - 15673
反应条件
sodium tetrahydroborate in methanol T=0°C; 0.333333 h;
参考文献
Hayashi, Yujiro; Yamaguchi, Junichiro; Sumiya, Tatsunobu; Hibino, Kazuhiro; Shoji, Mitsuru
Journal of Organic Chemistry, 2004 , vol. 69, # 18 p. 5966 - 5973
反应条件
bis(acetylacetonato) palladium; triethylaluminum; triphenylphosphine in tetrahydrofuran T=80°C; 4 h; further solvents tert-butanol, DMF, aceton, DMSO, CH3CN;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 30, # 8 p. 1506 - 1510
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , vol. 30, # 8 p. 1837 - 1842
反应条件
D-glucose in water T=33°C; 24 h; Microbiological reaction; optical yield given as percent ee;
参考文献
Monsalve, Leandro N.; Cerrutti, Patricia; Galvagno, Miguel A.; Baldessari, Alicia
Biocatalysis and Biotransformation, 2010 , vol. 28, # 2 p. 137 - 143
反应条件
hydrogen; nickel T=130°C;
参考文献
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 146, p. 1195
Annales de Chimie (Cachan, France), , vol. <8> 16, p. 92
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 148, p. 931
Annales de Chimie (Cachan, France), , vol. <8> 21, p. 513,520
反应条件
glyoxylic acid methylester methylhemiacetal; dihydrogen peroxide; [Mn2O3(1,4,7-trimethyl-1,4,7-triazacyclononane)2](PF6)2 in acetonitrile T=0°C;
参考文献
Tetrahedron Letters, , vol. 43, # 14 p. 2619 - 2622
反应条件
1.1: 91 percent / (S)-proline / CHCl3 / 2 h / 20 °C 2.1: NaBH4 2.2: H2 / PtO2 View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 43, # 9 p. 1109 - 1112
反应条件
5 Pd(II)/C(eggshell); hydrogen; triethylamine in methanol T=20°C; P=760.051 Torr; 3 h;
参考文献
Advanced Synthesis and Catalysis, , vol. 353, # 13 p. 2455 - 2465
反应条件
D-glucose in water T=33°C; 24 h; Microbiological reaction; optical yield given as percent ee;
参考文献
Monsalve, Leandro N.; Cerrutti, Patricia; Galvagno, Miguel A.; Baldessari, Alicia
Biocatalysis and Biotransformation, 2010 , vol. 28, # 2 p. 137 - 143