199620-14-9合成路线 （共 107 条）
反应条件
in tetrahydrofuran; anhydrous butyl ether (under N2); ratio aryl-compd.:Cr(CO)6 1:1, reflux for 24 h in Bu2O-THF; removal of the solvents, sublimation of the residue;
参考文献
Journal of Organometallic Chemistry, , vol. 455, # 1-2 p. 47 - 49
反应条件
in tetrahydrofuran refluxing in THF for 62 h at 130°C; extn. of solvent, chromy. (SiO2, hexane/benzene/ether (5:1:1)), IR, (1)H-NMR;
参考文献
Canadian Journal of Chemistry, , vol. 66, p. 2157 - 2160
反应条件
in neat (no solvent) in autoclave at 280°C;;
反应条件
in acetonitrile under N2; suspn. of Cr compd. in acetonitrile refluxed in the dark for 18 h; soln. cooled (ice bath); filtration; from filtrate, solvent removed to give crystals;
参考文献
Perez-Encabo, Alfonso; Perrio, Stephane; Slawin, Alexandra M. Z.; Thomas, Susan E.; Wierzchleyski, Adam T.; Williams, David J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 6 p. 629 - 642
反应条件
acetonitrile in acetonitrile refluxing, 15 min; cooling to room temp.; evapn.;
参考文献
Rigby, James H.; Ateeq, Humy S.; Charles, Nelly R.; Cuisiat, Stephane V.; Ferguson, Mark D.; Henshilwood, James A.; Krueger, A. Chris; Ogbu, Cyprian O.; Short, Kevin M.; Heeg
Journal of the American Chemical Society, 1993 , vol. 115, # 4 p. 1382 - 1396
反应条件
in benzene-d6 byproducts: H2; Irradiation (UV/VIS); (N2); UV irradn. of a soln. of boron compd. and Cr complex in C6D6 at 8°C for 1 h; not isolated, detected by NMR;
参考文献
Kawano, Yasuro; Uruichi, Mikio; Shimoi, Mamoru; Taki, Seitaro; Kawaguchi, Takayuki; Kakizawa, Taeko; Ogino, Hiroshi
Journal of the American Chemical Society, 2009 , vol. 131, # 41 p. 14946 - 14957
反应条件
palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; di-(1-adamantyl)-n-butylphosphine in toluene T=100°C; 16 h; Sealed tubeInert atmosphere;
参考文献
Wu, Xiao-Feng; Oschatz, Stefan; Sharif, Muhammad; Flader, Anika; Krey, Lisa; Beller, Matthias; Langer, Peter
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 18 p. 3581 - 3585
反应条件
formic acid in decalin refluxing for 6-7 h;
参考文献
Hrnciar, Peter; Toma, Stefan
Journal of Organometallic Chemistry, 1991 , vol. 413, # 1-3 p. 161 - 164
反应条件
in tetrahydrofuran; anhydrous butyl ether Flash chromy. (hexane/ether, 4/1).;
参考文献
Cambie, Richard C.; Clark, George R.; Gallagher, Stewart R.; Rutledge, Peter S.; Stone, Martin J.; Woodgate, Paul D.
Journal of Organometallic Chemistry, 1988 , vol. 342, p. 315 - 338
参考文献
Gmelin Handbook: Cr: Org.Verb., 1.6.1.2.7, page 258 - 289
Full Text Show Details
Whiting, M. C.
Patent: US3381023 , 1968 ;
