(1,2-二溴-2-苯乙烯基)苯合成路线 （共 18 条）
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
byproducts: diphenyl; addn. of the dibromo compd. in THF and the catalyst to a soln. of 1-heptynylzinc chloride in THF under cooling (-75°C), then room temp. (12 h); purifn. by liq. chromy. (Merck H 60 silica gel, hexane);
参考文献
Andreini, Bianca Patrizia; Benetti, Massimiliano; Carpita, Adriano; Rossi, Renzo
Gazzetta Chimica Italiana, 1988 , vol. 118, # 6 p. 469 - 474
反应条件
in tetrahydrofuran
addn. of THF to mixt. of the ethylene and Pd-complex (stirring, room temp., 36 h; then 65°C, 7 h); filtration; crystn. of the Pd-complex from the mother-liquor;
参考文献
Andreini, Bianca Patrizia; Benetti, Massimiliano; Carpita, Adriano; Rossi, Renzo
Gazzetta Chimica Italiana, 1988 , vol. 118, # 6 p. 469 - 474
反应条件
tetrakis(triphenylphosphine) palladium(0); 1-heptynylzinc chloride in tetrahydrofuran
12 h; Ambient temperature;
参考文献
Andreini, Bianca Patrizia; Benetti, Massimiliano; Carpita, Adriano; Rossi, Renzo
Gazzetta Chimica Italiana, 1988 , vol. 118, # 6 p. 469 - 474
参考文献
Limpricht; Schwanert
Chemische Berichte, 1871 , vol. 4, p. 380
Justus Liebigs Annalen der Chemie, 1868 , vol. 145, p. 349
参考文献
Otto
Journal fuer Praktische Chemie (Leipzig), 1896 , vol. <2> 53, p. 10
参考文献
Limpricht; Schwanert
Chemische Berichte, 1871 , vol. 4, p. 380
Justus Liebigs Annalen der Chemie, 1868 , vol. 145, p. 349
参考文献
Limpricht; Schwanert
Chemische Berichte, 1871 , vol. 4, p. 380
Justus Liebigs Annalen der Chemie, 1868 , vol. 145, p. 349
参考文献
Otto
Journal fuer Praktische Chemie (Leipzig), 1896 , vol. <2> 53, p. 10
