in diethyl ether mixt. of (CH3)3SiCH2MgCl and (CH3)3SiCl in ether; heating under evapn. of the ether during a longer period of time;;
参考文献
Sommer et al.
Journal of the American Chemical Society, 1947 , vol. 69, p. 980
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Sommer, L. H.; Mitch, F. A.; Godberg, G. M.
Journal of the American Chemical Society, 1949 , vol. 71, p. 2746 - 2750
sodium in toluene slow addn. of Na to a mixt. of (CH3)3SiCH2Cl, (CH3)3SiCl and toluene;;
参考文献
Gmelin Handbook: Si: MVol.C, 29, page 90 - 93
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Dow Corning Corp.
Patent: US2507513 , 1950 ;
C. I, 1951 , p. 119
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Dow Corning Corp.
Patent: US2511812 , 1950 ;
C. A., 1950 , p. 8362
in pentane under Ar, pentane condensed onto Sm-compd., addn. of HCCPh, allowed to warm to 0°C over a period of 20 min, stirred for 20 min, stirred at room temp. for 30 min; removal of solvent in vac., dissolved in toluene at 50°C, cooled to -15°C, filtered; elem. anal.;
参考文献
Nolan, Steven P.; Stern, David; Marks, Tobin J.
Journal of the American Chemical Society, 1989 , vol. 111, # 20 p. 7844 - 7853
in pentane under Ar, Ga-compd. and tetramethylheptanedione were mixed at -60 °C (molar ratio=1:2), mixt. was heated to room temp., stirring for 12 h; solvent was removed in vac., residue was dissolved in (i-Pr)2O, soln. was filtered, cooled to -50 °C;
参考文献
Uhl, Werner; Cuypers, Lars; Schueler, Kristiane; Spies, Thomas; Strohmann, Carsten; Lehmen, Klaus
Zeitschrift fur Anorganische und Allgemeine Chemie, 2000 , vol. 626, # 7 p. 1526 - 1534
