in tetrahydrofuran; toluene
Irradiation (UV/VIS); samples sealed under vac. in silica tubes, photolyzed with light from 500 W high pressure Hg arc at -14 or -34°C; not isolated; detected by ESR;
参考文献
Brindley, Peter B.; Davies, Alwyn G.; Hawari, Jalal A.-A.
Journal of Organometallic Chemistry, 1983 , vol. 250, # 1 p. 247 - 256
in toluene
Irradiation (UV/VIS); sample sealed under vac. in silica tubes, photolyzed with light from 500 W high pressure Hg arc at -80 to -6°C; not isolated; detected by ESR;
参考文献
Brindley, Peter B.; Davies, Alwyn G.; Hawari, Jalal A.-A.
Journal of Organometallic Chemistry, 1983 , vol. 250, # 1 p. 247 - 256
in toluene
Irradiation (UV/VIS); sample sealed under vac. in silica tubes, photolyzed with light from 500 W high pressure Hg arc at -33°C; not isolated; detected by ESR;
参考文献
Brindley, Peter B.; Davies, Alwyn G.; Hawari, Jalal A.-A.
Journal of Organometallic Chemistry, 1983 , vol. 250, # 1 p. 247 - 256
in toluene
Irradiation (UV/VIS); sample sealed under vac. in silica tubes, photolyzed with light from 500 W high pressure Hg arc at -70 to -14°C; not isolated; detected by ESR;
参考文献
Brindley, Peter B.; Davies, Alwyn G.; Hawari, Jalal A.-A.
Journal of Organometallic Chemistry, 1983 , vol. 250, # 1 p. 247 - 256
→
反应条件
T=24.9°C; P=0.5 Torr; different α,β-unsaturated molecules; Rate constantMechanismProduct distribution;
参考文献
McDonald, Richard N.; Chowdhury, A. Kasem
Journal of the American Chemical Society, 1980 , vol. 102, # 19 p. 6146 - 6147
