in not given
dissolving POCl3 in abs. HNO3; react. under evolution of Cl2 and NOCl; react. of POCl3 with HNO3 forming PO(NO3)3 and HCl, react. of HCl with HNO3 forming H2O, Cl2 and NOCl; react. of PO(NO3)3 with H2O forming HNO3 and HPO3;;
参考文献
Jander, G.; Wendt, H.
Z. Anorg. Chem., 1949 , vol. 258, p. 1 - 14
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Gmelin Handbook: P: MVol.C, 204, page 467 - 469
Thomas, J. H.; Woodman, G. R.
Transactions of the Faraday Society, 1967 , vol. 63, p. 2728 - 2736
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Gmelin Handbook: C: MVol.C2, 1.9.2, page 145 - 145
in neat (no solvent)
fuming H2SO4 (containig 20percent SO3); heated at 100°C;;
参考文献
Secareano, S.
Bulletin de la Societe Chimique de France, 1927 , vol. 41, p. 630 - 631
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Gmelin Handbook: S: MVol.B3, 51, page 1641 - 1643
in neat (no solvent)
byproducts: AgCl; excess of AgNO2, heating for 6 h 80°C, sealed tube;;
参考文献
Battegay, M.; Denivelle, L.
Bulletin de la Societe Chimique de France, 1930 , vol. 47, p. 606 - 612
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Gmelin Handbook: S: MVol.B3, 18, page 1567 - 1569
in gaseous matrix
Kinetics; react. of NCl (prepared from N3Cl and Cl-radicals) and ClO (prepared from Cl and OClO) in a discharge-flow system at 295 K with He as carrier gas (1 Torr); determination by mass spectroscopy;
参考文献
Clyne, Michael A. A.; MacRobert, Alexander J.; Stief, Louis J.
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1985 , vol. 81, p. 159 - 168
