1-(三氟甲基磺酰基氧基)环庚烯合成路线 （共 10 条）
反应条件
1: cycloheptanone With lithium diisopropyl amide in tetrahydrofuran T=-78°C; 0.75 h; 2: N,N-bis(trifluoromethanesulfonyl)aniline in tetrahydrofuran T=-78 - 25°C;
参考文献
Xu, Zhengren; Wang, Qian; Zhu, Jieping
Angewandte Chemie - International Edition, 2013 , vol. 52, # 11 p. 3272 - 3276
Angew. Chem., 2013 , vol. 125, # 11 p. 3354 - 3358,5
反应条件
pyridine in dichloromethane 1.) -78 deg C, 0.5 h, 2.) 25 deg C, 22 h;
参考文献
Kamekawa, Hisato; Senboku, Hisanori; Tokuda, Masao
Tetrahedron Letters, 1998 , vol. 39, # 12 p. 1591 - 1594
反应条件
in neat (no solvent) equiv. amts. of educts, at -15 - 0°C, 3 days;
参考文献
Dueber, T. E.; Stang, P. J.; Pfeifer, W. D.; et al.
Angewandte Chemie, 1970 , vol. 9, p. 521 - 522
Angewandte Chemie, 1970 , vol. 82, p. 517 - 518
反应条件
1: 2-propen-2-ylmagnesium bromide With zinc dibromide in tetrahydrofuran T=20°C; 2: cyclohept-1-en-1-yl trifluoromethanesulfonate; carbon monoxide With zinc dibromide; nickel dichloride in tetrahydrofuran; dimethyl sulfoxide T=50°C; Negishi coupling; P=760.051 Torr; 0.333333 h; Further stages.;
参考文献
Wang, Qiaoling; Chen, Chuo
Tetrahedron Letters, 2008 , vol. 49, # 18 p. 2916 - 2921
反应条件
triphenylphosphine; Co(acetylacetonate)3 in tetrahydrofuran T=20°C; 3 h;
参考文献
Shirakawa, Eiji; Imazaki, Yusuke; Hayashi, Tamio
Chemistry Letters, 2008 , vol. 37, # 6 p. 654 - 655
参考文献
Stang,P.J.; Anderson,A.G.
Journal of the American Chemical Society, 1978 , vol. 100, p. 1520 - 1525
反应条件
[RuIII(2,4-pentanedionato)3]; n-butyl-magnesium chloride; lithium chloride in tetrahydrofuran T=60°C; 3 h; Inert atmosphere;
参考文献
Shirakawa, Eiji; Imazaki, Yusuke; Hayashi, Tamio
Chemical Communications, 2009 , # 34 p. 5088 - 5090
反应条件
[RuIII(2,4-pentanedionato)3]; 1,10-phenanthroline; ethylmagnesium bromide; lithium bromide in tetrahydrofuran
T=60°C; 1 h; Inert atmosphere;
参考文献
Shirakawa, Eiji; Imazaki, Yusuke; Hayashi, Tamio
Chemical Communications, 2009 , # 34 p. 5088 - 5090
反应条件
{RuCl2(1-methyl-4-(1-methylethyl)benzene)}2; 3,4,7,8-tetra-methyl-1,10-phenanthroline; zinc in 1,3-dimethyl-imidazolidin-2-one
T=120°C; 24 h; Inert atmosphere;
参考文献
Imazaki, Yusuke; Shirakawa, Eiji; Hayashi, Tamio
Tetrahedron, 2011 , vol. 67, # 52 p. 10212 - 10215
反应条件
in N,N-dimethyl-formamide
T=5°C; electrolysis at 10 mA/cm2; 0.1M Bu4NBF4; platinum plate cathode, magnesium rod anode;
参考文献
Kamekawa, Hisato; Senboku, Hisanori; Tokuda, Masao
Tetrahedron Letters, 1998 , vol. 39, # 12 p. 1591 - 1594
