6-甲基-2,4-庚二酮合成路线 （共 41 条）
反应条件
water; β-diketone hydrolase T=30°C; 15 h; in phosphate buffer at pH 7.0; substrate specifity of catalyst; Product distribution;
参考文献
Sakai, Kiyofumi; Hamada, Nobutake; Watanabe, Yasuto
Agricultural and Biological Chemistry, 1986 , vol. 50, # 4 p. 989 - 996
参考文献
Kutz; Adkins
Journal of the American Chemical Society, 1930 , vol. 52, p. 4036,4040
参考文献
Kutz; Adkins
Journal of the American Chemical Society, 1930 , vol. 52, p. 4036,4040
反应条件
hydrogen; Ni-Gr2 in methanol
T=120°C; P=38000 Torr; 18 h;
参考文献
Savoia, Diego; Tagliavini, Emilio; Trombini, Claudio; Umani-Ronchi, Achille
Journal of Organic Chemistry, 1981 , vol. 46, p. 5344 - 5348
反应条件
diethyl ether; nickel
T=125°C; P=110326 - 147102 Torr; Hydrogenation;
参考文献
Sprague; Adkins
Journal of the American Chemical Society, 1934 , vol. 56, p. 2669,2671
反应条件
T=85°C; P=110326 - 147102 Torr; Hydrogenation;
参考文献
Sprague; Adkins
Journal of the American Chemical Society, 1934 , vol. 56, p. 2669,2671
反应条件
T=125°C; P=110326 - 147102 Torr; Hydrogenation;
参考文献
Sprague; Adkins
Journal of the American Chemical Society, 1934 , vol. 56, p. 2669,2671
反应条件
1: Raney nickel; methanol / 100 °C / Hydrogenation.unter Stickstoffdruck
2: oxalic acid / Durch Destillation
View Scheme
参考文献
Stutsman; Adkins
Journal of the American Chemical Society, 1939 , vol. 61, p. 3306
反应条件
piperidine in ethanol
参考文献
ICN Pharmaceuticals, Inc.
Patent: US4093617 A1, 1978 ;
US 4093617 A
反应条件
hydrogen; Ni-Gr2 in methanol
T=90°C; P=22800 Torr; 22 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Savoia, Diego; Tagliavini, Emilio; Trombini, Claudio; Umani-Ronchi, Achille
Journal of Organic Chemistry, 1981 , vol. 46, p. 5344 - 5348
