copper(l) iodide; sodium acetate in 1,2-dichloro-ethane T=25°C; 3 h;

copper(l) iodide; sodium acetate in 1,2-dichloro-ethane T=25°C; 3 h;

Fe(III)-montmorillonite in nitrobenzene T=200°C; Acylation; 3 h;

sodium acetate; triphenylphosphine; palladium diacetate in tetrahydrofuran T=100°C; tandem Heck-aldol reaction; 24 h;

in N,N-dimethyl-formamide T=90°C; 24 h; Schlenk techniqueInert atmosphere;

1: N,N-dimethyl-formamide / 15 h / 25 °C 2: pyridine / 20 h / 20 °C 3: N-bromosuccinmide; 2,2'-azo-bisisobutyronitrile / tetrachloromethane / 1.5 h / 70 °C 4: diisobutylaluminium hydride / tetrahydrofuran / 1.25 h / 0 - 5 °C 5: tetrabutyl ammonium fluoride / dimethyl sulfoxide / 4 h / 25 °C 6: 3-chloro-benzenecarboperoxoic acid / chloroform / 2.25 h / 20 °C / Cooling with ice 7: perchloric acid / water / 25 °C View Scheme

1: N,N-dimethyl-formamide / 15 h / 25 °C 2: pyridine / 20 h / 20 °C 3: N-bromosuccinmide; 2,2'-azo-bisisobutyronitrile / tetrachloromethane / 1.5 h / 70 °C 4: diisobutylaluminium hydride / tetrahydrofuran / 1.25 h / 0 - 5 °C 5: tetrabutyl ammonium fluoride / dimethyl sulfoxide / 4 h / 25 °C 6: 3-chloro-benzenecarboperoxoic acid / chloroform / 2.25 h / 20 °C / Cooling with ice 7: perchloric acid / water / 25 °C View Scheme

暂无反应条件数据

phosphorus pentoxide T=180 - 200°C;

diethyl ether