2-叔丁基-4-氰基吡啶合成路线 （共 16 条）
反应条件
(NH4)2S2O8; silver nitrate; trifluoroacetic acid in water; chlorobenzene T=50°C; 2 h;
参考文献
YALE UNIVERSITY
Patent: WO2008/30408 A2, 2008 ;
Location in patent: Page/Page column 32-33 ;
WO 2008/030408 A2
反应条件
(NH4)2S2O8; trifluoroacetic acid; silver nitrate in water; chlorobenzene T=50°C; 2 h;
参考文献
Fontana; Minisci; Barbosa, M. C. Nogueira; Vismara
Tetrahedron, 1990 , vol. 46, # 7 p. 2525 - 2538
反应条件
dipotassium peroxodisulfate; sulfuric acid; copper diacetate; silver nitrate in water T=57°C; 3 h; without cupric acetate, various temperatures and acidities, (NH4)2S2O8 for K2S2O8; Product distributionRate constantMechanism;
参考文献
Citterio, Attilio; Minisci, Francesco; Franchi, Valeria
Journal of Organic Chemistry, 1980 , vol. 45, # 23 p. 4752 - 4757
反应条件
trichlorophosphate T=120 - 130°C;
参考文献
Libermann et al.
Bulletin de la Societe Chimique de France, 1958 , p. 687,691
反应条件
sodium peroxodisulphate; sulfuric acid; silver nitrate in dichloromethane; water 2 h; Heating;
参考文献
Coppa, Fausta; Fontana, Francesca; Lazzarini, Edoardo; Minisci, Francesco; Pianese, Giuseppe; Zhao, Lihua
Chemistry Letters, 1992 , # 7 p. 1295 - 1298
反应条件
toluene-4-sulfonic acid; potassium iodide in dimethyl sulfoxide 24 h; UV-irradiation;
参考文献
Kim; Jeon; Han; Park; Jun
Journal of the Chemical Society. Perkin Transactions 1, 2001 , # 17 p. 2035 - 2039
反应条件
dipotassium peroxodisulfate; sulfuric acid; ammonia; silver nitrate 1) water, CH3CN, 80 deg C, 2) water, 25 deg C; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Citterio, Attilio; Minisci, Francesco; Franchi, Valeria
Journal of Organic Chemistry, 1980 , vol. 45, # 23 p. 4752 - 4757
反应条件
dipotassium peroxodisulfate; sulfuric acid; ammonia; silver nitrate 1) water, 80 deg C, 2) 90 deg C, water; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Citterio, Attilio; Minisci, Francesco; Franchi, Valeria
Journal of Organic Chemistry, 1980 , vol. 45, # 23 p. 4752 - 4757
反应条件
dipotassium peroxodisulfate; sulfuric acid; ammonia; silver nitrate 1) water, 80 deg C, 2) water; Multistep reaction. Further byproducts given. Yields of byproduct given;
参考文献
Citterio, Attilio; Minisci, Francesco; Franchi, Valeria
Journal of Organic Chemistry, 1980 , vol. 45, # 23 p. 4752 - 4757
反应条件
1: aqueous NH3 2: POCl3 / 120 - 130 °C View Scheme
参考文献
Libermann et al.
Bulletin de la Societe Chimique de France, 1958 , p. 687,691
