环戊基铁(II) 二羰基二聚体合成路线 （共 74 条）
反应条件
in dichloromethane
react. of equimol. amt. of Fe complex with freshly distd. SO2Cl2 at room temp.;; high yield;;
参考文献
Manning, A. R.; McNally, Gerald; Davis, Reg; Rowland, Christopher C.
Journal of Organometallic Chemistry, 1983 , vol. 259, # 2 p. C15 - C16
反应条件
in chloroform
1 h; RefluxInert atmosphere;
参考文献
El-Tarhuni, Sarah; Ho, Monica; Kawser, Mohammed H.; Shi, Saiqin; Whiteley, Mark W.
Journal of Organometallic Chemistry, 2014 , vol. 752, p. 30 - 36
反应条件
in acetonitrile
Electrolysis; Hg-electrode, 0.25 M Bu4NBF4, 20°C; electrolysis of Fe-complex (-1.85 V vs. Ag/AgCl), addn. of aryl halide, electrolysis at -1.90 to -1.55 V;
参考文献
Magdesieva; Kukhareva; Shaposhnikova; Artamkina; Beletskaya; Butin
Journal of Organometallic Chemistry, 1996 , vol. 526, # 1 p. 51 - 58
反应条件
o-C6H4(CN)2 in acetonitrile
Electrolysis; Hg-electrode, 0.25 M Bu4NBF4, 20°C; electrolysis of Fe-complex (-1.85 V vs. Ag/AgCl), addn. of aryl halide and o-C6H4(CN)2, electrolysis at -1.80 V;
参考文献
Magdesieva; Kukhareva; Shaposhnikova; Artamkina; Beletskaya; Butin
Journal of Organometallic Chemistry, 1996 , vol. 526, # 1 p. 51 - 58
反应条件
iodine in not given
Fe-complex was reacted with I2;
参考文献
Li, Hong-ju; Turnbull, Mark M.
Journal of Organometallic Chemistry, 1991 , vol. 419, p. 244 - 250
反应条件
in methanol; benzene
A soln. of reagents in benzene/methanol, molar ratio 1:1, N2 atm., room temp., in the dark;; crystals were filtered off; washed with cold ether and dried; the filtrate was evapd. to dryness, recrystd. from toluene-pentane; elem. anal.;;
参考文献
Kumar, Rajesh; Manning, A. R.; Murray, Paul T.
Journal of Organometallic Chemistry, 1987 , vol. 323, p. 53 - 66
反应条件
in acetonitrile
byproducts: nitrobenzene; Electrolysis; electrolysis at -1.5 V;
参考文献
Magdesieva, T. V.; Kukhareva, I. I.; Artamkina, G. A.; Butin, K. P.; Beletskaya, I. P.
Journal of Organometallic Chemistry, 1994 , vol. 468, # 1-2 p. 213 - 222
反应条件
in acetonitrile
Electrolysis; Hg-cathode, 0.25 M Bu4NBF4; treatment of Fe-complex at -1.8 V vs. Ag/AgCl, addn. of C6H4I2, switching potential between -1.55 and -1.75 V at 500mV/s for 3 h;
参考文献
Magdesieva, T.V.; Kukhareva, I. I.; Artamkina, G. A.; Beletskaya, I. P.; Butin, K. P.
Journal of Organometallic Chemistry, 1995 , vol. 487, # 1-2 p. 163 - 166
反应条件
in toluene
refluxing (1 h); recrystn. (CH2Cl2/hexane); elem. anal. of InI(Fe(CO)2Cp)2;
参考文献
Clarkson, L. M.; Norman, N. C.; Farrugia, L. J.
Journal of Organometallic Chemistry, 1990 , vol. 390, # 1 p. C10 - C15
反应条件
palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; tri-cyclo-hexyl-phosphine in toluene
T=110°C; 12 h;
参考文献
Nakaya, Ryotaro; Yorimitsu, Hideki; Oshima, Koichiro
Chemistry Letters, 2011 , vol. 40, # 9 p. 904 - 906
