1-甲基-4-(2-甲基-2-丙烯-1-基)苯合成路线 (共 9 条)
反应条件
Pd(phenylimino)acenaphthene dimethyl fumarate in N,N-dimethyl-formamide
T=50°C; 16 h;
参考文献
Asselt, Rob van; Elsevier, Cornelis J.
Tetrahedron, 1994 , vol. 50, # 2 p. 323 - 334
反应条件
Fe(acac)3 in tetrahydrofuran
T=25°C; 3 h; Inert atmosphere;
参考文献
Volla, Chandra M. R.; Markovic, Dean; Dubbaka, Srinivas Reddy; Vogel, Pierre
European Journal of Organic Chemistry, 2009 , # 36 p. 6281 - 6288
反应条件
sodium methylate in methanol
参考文献
Bunnett,J.F.; Sridharan,S.
Journal of Organic Chemistry, 1979 , vol. 44, # 9 p. 1458 - 1463
反应条件
1: (i) Mg, (ii) /BRN= 635680/, (iii) SOCl2, Py
2: NaOMe / methanol
View Scheme
参考文献
Bunnett,J.F.; Sridharan,S.
Journal of Organic Chemistry, 1979 , vol. 44, # 9 p. 1458 - 1463
反应条件
hexacarbonyl molybdenum
T=110°C; 72 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Shimizu, Isao; Sakamoto, Toshiaki; Kawaragi, Saeko; Maruyama, Yooichiro; Yamamoto, Akio
Chemistry Letters, 1997 , # 2 p. 137 - 138
反应条件
(i) Mg, (ii) /BRN= 878160/; Multistep reaction;
参考文献
Ruechardt,C.
Chemische Berichte, 1961 , vol. 94, p. 2609 - 2623
参考文献
Urry; Nicolaides
Journal of the American Chemical Society, 1952 , vol. 74, p. 5163,5167
参考文献
Trubek Labor. Inc.
Patent: US2454779 , 1947 ;
反应条件
activation volume, var.: temp., pressure; Rate constantMechanismProduct distribution;
参考文献
Sera, Akira; Yamada, Hiroaki; Masaki, Hitoshi
Chemistry Letters, 1980 , p. 1533 - 1536