(三甲基硅基)乙酸乙酯合成路线 （共 118 条）
反应条件
boron trifluoride diethyl etherate 1.)ethyl trimethylsilylacetate, ether, -78 grad C, warmed to rt., stirred overnight, 2.) BF3OEt2, CH2Cl2, 2 h, rt.; Yield given. Multistep reaction;
参考文献
Larson, Gerald L.; Hernandez, David
Tetrahedron Letters, 1982 , vol. 23, # 10 p. 1035 - 1038
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran 5 h; Ambient temperature;
参考文献
Nakamura, Eiichi; Hashimoto, Koichi; Kuwajima, Isao
Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 3 p. 805 - 808
反应条件
iodine cloride in tetrachloromethane 0.5 h; Ambient temperature;
参考文献
Bordeau, M.; Djamei, S. M.; Dunogues, J.
Bulletin de la Societe Chimique de France, 1986 , # 3 p. 413 - 417
反应条件
cesium fluoride T=100°C; 24 h;
参考文献
Latouche, Regine; Texier-Boullet, Francoise; Hamelin, Jack
Tetrahedron Letters, 1991 , vol. 32, # 9 p. 1179 - 1182
反应条件
magnesium oxide; cesium fluoride 0.05 h; under microwave irradiation;
参考文献
Latouche, Regine; Texier-Boullet, Francoise; Hamelin, Jack
Tetrahedron Letters, 1991 , vol. 32, # 9 p. 1179 - 1182
反应条件
(i) dicyclohexylamine, nBuLi, (ii) /BRN= 385735/; Multistep reaction;
参考文献
Shimoji,K. et al.
Journal of the American Chemical Society, 1974 , vol. 96, # 5 p. 1620 - 1621
反应条件
lithium diisopropyl amide 1.) THF, hexane, -78 deg C, 1 h, 2.) a) from -78 deg C to room temp., 1 h, b) room temp., 4 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Tsuge, Otohiko; Sone, Kazuhiro; Urano, Satoshi; Matsuda, Koyo
Journal of Organic Chemistry, 1982 , vol. 47, # 26 p. 5171 - 5177
反应条件
tetrabutyl ammonium fluoride; fluorine 1.) CH2Cl2, -50 deg C, 2.) CH2Cl2, a) -50 deg C, 1 h, b) -50 to 0 deg C, 1 h, c) 0 deg C, 0.5 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Kiselyov, Alexander S.; Strekowski, Lucjan
Journal of Organic Chemistry, 1993 , vol. 58, # 16 p. 4476 - 4478
参考文献
Gold; Sommer; Whitmore
Journal of the American Chemical Society, 1948 , vol. 70, p. 2874
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Gmelin Handbook: Si: MVol.C, 4, page 14 - 18
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran 26 h; Ambient temperature;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 54, # 3 p. 805 - 808
