in solid matrix Irradiation (UV/VIS); photolysis of solid matrix Ar:OCS:PCl3=100:1:1 using unfiltered emission of Hg arc 20 K for 60 min;; not isolated; detn. in solid matrix by IR spectroscopy;;
参考文献
Hawkins, Michael; Almond, Matthew; Downs, Anthony J.
Journal of Physical Chemistry, 1985 , vol. 89, # 15 p. 3326 - 3334
byproducts: SSF2; the sepd. fluorine and COS in a high vac. app., cooling to -196°C and -78°C, resp., after the react. cooling the gas to -196°C, further byproducts; continuous evapn. of CO; condensation, cooling to -78°C, evapn. of volatile compds. for 0.5 h, detected by IR;
参考文献
Haas, A.; Willner, H.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1980 , vol. 462, p. 57 - 60