potassium hydroxide; Na2B2O7 in water T=78°C; 0.5 h; isomerization equilibrium; degradation to acids; varying time, borate molar ratio from 0.4 to 4.0; Rate constantProduct distributionMechanism;
参考文献
Bruijn, J. M. de; Kieboom, A. P. G.; Bekkum, H. van
Recueil des Travaux Chimiques des Pays-Bas, 1987 , vol. 106, # 2 p. 35 - 43
potassium hydroxide in water T=78°C; 0.333333 h; isomerization equilibrium; degradation to acids; varying time, OH(1-) concentration 0.001 M to O.1 M; also in presence of Ca(2+) up to 0.06 M; Rate constantProduct distributionMechanism;
参考文献
Bruijn, J. M. de; Kieboom, A. P. G.; Bekkum, H. van
Recueil des Travaux Chimiques des Pays-Bas, 1987 , vol. 106, # 2 p. 35 - 43
beim Behandeln mit einem basischen Anionenaustauscher;
参考文献
Sowden
Journal of the American Chemical Society, 1954 , vol. 76, p. 4487
Full Text View citing articles Show Details
Buhler et al.
Journal of the American Chemical Society, 1955 , vol. 77, p. 481
