乙酸-3-甲基-3-丁烯-1-醇酯合成路线 （共 36 条）
反应条件
pyridine; sulfuryl dichloride; lithium perchlorate
1) -60 deg C, CH2Cl2, 20 min, 2) DMF, 70 deg C, 3 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Veselovskii, V. V.; Skorobogatov, S. P.; Novikova, M. A.; Moiseenkov, A. M.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1990 , vol. 39, # 3.1 p. 513 - 516
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1990 , # 3 p. 591 - 594
反应条件
1: (PhCO)2O2 / cyclohexane / 24 h / 80 °C
2: (i) KOH, MeOH, (ii) NaOCl, Na2CO3
View Scheme
参考文献
Julia,M. et al.
Bulletin de la Societe Chimique de France, 1976 , p. 519 - 524
反应条件
anhydrous magnesium perchlorate
T=20°C; 0.5 h;
参考文献
Bartoli, Giuseppe; Bosco, Marcella; Dalpozzo, Renato; Marcantoni, Enrico; Massaccesi, Massimo; Rinaldi, Samuele; Sambri, Letizia
Synlett, 2003 , # 1 p. 39 - 42
反应条件
acetic acid
T=190°C; P=27213.8 Torr;
参考文献
Blomquist; Verdol
Journal of the American Chemical Society, 1955 , vol. 77, p. 78
反应条件
sulfuric acid in ethyl acetate
T=90°C; 9 h; metal ampul; Further byproducts given;
参考文献
Rakhmankulov, I. L.; Kantor, E. A.; Rakhmankulov, D. L.
J. Appl. Chem. USSR (Engl. Transl.), 1980 , vol. 53, # 6 p. 1367 - 1372,1093 - 1097
反应条件
trichlorophosphate in pyridine
15 h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Badet,B.; Julia,M.; Mallet,J.M.
Tetrahedron, 1988 , vol. 44, p. 2913
反应条件
triethylamine in dichloromethane
参考文献
Breuilles, Pascal; Uguen, Daniel
Bulletin de la Societe Chimique de France, 1988 , # 4 p. 705 - 720
参考文献
Eggerer; Lynen
Justus Liebigs Annalen der Chemie, 1960 , vol. 630, p. 58,70
反应条件
hydrogenchloride; diethyl ether
und Erhitzen des Reaktionsprodukts mit Eisessig und Natriumacetat;
参考文献
Ostromysslenski
Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1915 , vol. 47, p. 1982
Chem. Zentralbl., 1916 , vol. 87, # II p. 307
反应条件
T=190°C; P=37 Torr; weitere Produkte: 4-Acetoxy-2-acetoxymethyl-but-1-en und 1,3-Diacetoxy-3-methyl-butan;
参考文献
Blomquist; Verdol
Journal of the American Chemical Society, 1955 , vol. 77, p. 78
