in ethanol; H2O
soln. of 4,4'-bipyridine in EtOH slowly added to aq. soln. of Cu(BF4)2, slurry stirred at room temp. for 4 h; according to A. Baiker et al., J. Catal. 257 (2008) 390 and Chem. Eur. J. 15 (2009) 12255; solid filtered off, washed (H2O, EtOH), dried (room temp., air), treatedat 100°C and 50 Pa for 2 h; XRD;
参考文献
Jiang, Dongmei; Mallat, Tamas; Meier, Daniel M.; Urakawa, Atsushi; Baiker, Alfons
Journal of Catalysis, 2010 , vol. 270, # 1 p. 26 - 33
1.1: sulfuric acid; silver nitrate / H2O / 0.5 h / 110 °C
1.2: ammonium persulfate / H2O / 0.5 h / Heating
2.1: 23.9 percent / potassium permanganate / H2O / 12 h / Heating
View Scheme
参考文献
Chen, Chun-Long; Ellsworth, Joseph M.; Goforth, Andrea M.; Smith, Mark D.; Su, Cheng-Yong; Zur Loye, Hans-Conrad
Dalton Transactions, 2006 , # 44 p. 5278 - 5286
Barltrop, John A.; Jackson, Andrew C.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1984 , # 3 p. 367 - 372
