perchloric acid; bromamine T in water T=29.9°C; 24 h; other temperatures, E(act.), ΔH(excit.), ΔS(excit.), ΔG(excit.); various concentrations of the oxidant and substrate; effect of added bromide and p-toluenesulphonamide, varying ionic strength and dielectric constant of the medium; KineticsMechanismThermodynamic data;
参考文献
Gowda, B. Thimme; Rao, R. Vijayalakshmi
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1988 , vol. 27, # 1 p. 34 - 38
perchloric acid; chromic acid in water T=50°C; ΔE(excit.), ΔS(excit.); effect of pyridine, various salts and concentrations; reaction order; Rate constantThermodynamic dataMechanism;
参考文献
Gowda, B. Thimme; Sherigara, B. S.
Journal of the Indian Chemical Society, 1987 , vol. 64, # 3 p. 158 - 162
perchloric acid; water in acetic acid T=34.9°C; further temperatures; also with AcONa, NaClO4 and without HClO4; EA, ΔH(excit), ΔS(excit), ΔG(excit); KineticsMechanismThermodynamic data;
参考文献
Gowda, B. Thimme; Sherigara, B. S.
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1987 , vol. 26, # 11 p. 930 - 935