2,3-二甲基-2-丁烯合成路线 (共 833 条)
反应条件
1: concentrated aqueous H2SO4; acetic acid 2: AlCl3 View Scheme
参考文献
Wood,T.F. et al.
Journal of Organic Chemistry, 1963 , vol. 28, p. 2248 - 2255
反应条件
potassium fluoride in triglyme (triethylene glycol dimethyl ether) T=20°C;
参考文献
Journal of Fluorine Chemistry, , vol. 132, # 10 p. 815 - 828
反应条件
in hexane 50 h; Irradiation;
参考文献
Cantrell, Thomas S.; Allen, Andrew C.
Journal of Organic Chemistry, 1989 , vol. 54, # 1 p. 135 - 139
反应条件
sulfur trioxide depending on reaction time and temperature; Product distribution;
参考文献
Roberts, David W.; Jackson, Philip S.; Saul, Colin D.; Clemett, Colin J.
Tetrahedron Letters, 1987 , vol. 28, # 29 p. 3383 - 3386
反应条件
sodium hydroxide; dihydrogen peroxide in tetrahydrofuran; water; toluene
参考文献
Roussel Uclaf
Patent: US5180741 A1, 1993 ;
反应条件
T=25°C; 1 h; IrradiationOsram 200 W XE mercury lamp, Pyrex filter or 25 deg C dark thermolysis (1h); Yield given. Yields of byproduct given;
参考文献
Moss, Robert A.; Wlostowska, Joanna
Tetrahedron Letters, 1988 , vol. 29, # 21 p. 2559 - 2562
反应条件
T=25°C; competition reaction with tetramethylethylene (TME); Product distribution;
参考文献
Moss, Robert A.; Wlostowska, Joanna
Tetrahedron Letters, 1988 , vol. 29, # 21 p. 2559 - 2562
反应条件
in hexane 3.25 h; Ambient temperatureIrradiationvar. wavelength; Product distribution;
参考文献
Photochemistry and Photobiology, , vol. 66, # 5 p. 566 - 568
反应条件
ozone P=4.1 Torr; 0.000777778 h; reaction in gas phase; mass spectrum of ozone and title compound; Product distributionMechanism;
参考文献
Martinez, Richard I.; Herron, John T.; Huie, Robert E.
Journal of the American Chemical Society, 1981 , vol. 103, # 13 p. 3807 - 3820
反应条件
ozone in gaseous matrix T=24.9°C; P=700 Torr; examination of the formation of the secondary ozonides; variation of aldehyde partial pressure; study of addition of further aldehyde; Product distributionMechanism;
参考文献
Niki, H.; Maker, P. D.; Savge, C. M.; Breitenbach, L. P.; Hurley, M. D.
Journal of Physical Chemistry, 1987 , vol. 91, # 4 p. 941 - 946