2,4-二甲基-3-戊酮合成路线 (共 349 条)
反应条件
titanium tetrachloride; lithium in THF-d8 (tetrahydrofuran-d8) T=20°C; McMurry reaction; 24 h; Product distribution; Further Variations:Reagentsmolar ratio;
参考文献
Villiers, Claude; Ephritikhine, Michel
Chemistry - A European Journal, 2001 , vol. 7, # 14 p. 3043 - 3051
参考文献
Stas
Bulletin des Societes Chimiques Belges, 1926 , vol. 35, p. 382
Chem. Zentralbl., 1927 , vol. 98, # I p. 715
反应条件
tetrahydrofuran in toluene T=0°C; Grignard reaction; addition; reduction; Product distribution; Further Variations:Reagents;
参考文献
Tuulmets, Ants; Sassian, Meeri
Journal of Organometallic Chemistry, 1999 , vol. 586, # 2 p. 145 - 149
反应条件
tetrahydrofuran in toluene T=0°C; Grignard reaction; addition; reduction; Product distribution; Further Variations:Reagents;
参考文献
Tuulmets, Ants; Sassian, Meeri
Journal of Organometallic Chemistry, 1999 , vol. 586, # 2 p. 145 - 149
反应条件
ethoxymagnesium chloride in diethyl ether T=20°C; Kinetics; Further Variations:Reagents;
参考文献
Panov, Dmitri; Tuulmets, Ants; Nguyen, Binh T.
Journal of Organometallic Chemistry, 2006 , vol. 691, # 19 p. 4076 - 4079
反应条件
in diethyl ether T=25°C; 1 h; effects of salts (MeOK, t-BuOK, PhOK, (Me2NCH2)2CHOK, MeONa, MeOLi, t-BuOLi, Bu4NBr, BzlEt3NCl), 2,1,1-cryptand and 2,2,2-cryptand; Product distribution;
参考文献
Richey, Herman G.; DeStephano, Joseph P.
Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3281 - 3286
参考文献
Stas
Bulletin des Societes Chimiques Belges, 1926 , vol. 35, p. 382
Chem. Zentralbl., 1927 , vol. 98, # I p. 715
Full Text Show Details
Stas
Bulletin des Societes Chimiques Belges, 1925 , vol. 34, p. 188
Chem. Zentralbl., 1925 , vol. 96, # II p. 1268
Full Text Show Details
Conant; Blatt
Journal of the American Chemical Society, 1929 , vol. 51, p. 1233
参考文献
Stas
Bulletin des Societes Chimiques Belges, 1926 , vol. 35, p. 382
Chem. Zentralbl., 1927 , vol. 98, # I p. 715
Full Text Show Details
Stas
Bulletin des Societes Chimiques Belges, 1925 , vol. 34, p. 188
Chem. Zentralbl., 1925 , vol. 96, # II p. 1268
Full Text Show Details
Conant; Blatt
Journal of the American Chemical Society, 1929 , vol. 51, p. 1233
参考文献
Conant; Blatt
Journal of the American Chemical Society, 1929 , vol. 51, p. 1233
反应条件
potassium hydroxide; Ru(CF3CO2)CO(PPh3)2 T=140°C; 200 h; Equilibrium constant;
参考文献
Graser, Barbara; Strohmeier, Walter; Marcec, Radovan; Steigerwald, Hannelore
Berichte der Bunsen-Gesellschaft, 1981 , vol. 85, # 7 p. 671 - 677