RhH2(O2COH)(P(i-Pr)3)2 in tetrahydrofuran T=120°C; 20 h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
in tetrahydrofuran react. of equimolar amts. of HBCl2 and hexene-1 at 20-25°C for 9 d, followed by hydrolysis and oxidn.; ratio of 1-hexanol and 2-hexanol 99:1;
参考文献
Zweifel
Journal of Organometallic Chemistry, 1967 , vol. 9, p. 215,218, 219
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Gmelin Handbook: B: B-Verb.9, 1.4.2.3, page 38 - 40
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 31, p. 1852 - 1858
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 9 p. 2100 - 2106
