1-环己基-2-苯基-1-乙酮合成路线 （共 31 条）
反应条件
1.1: iPrMgCl*LiCl / tetrahydrofuran / 1.5 h / -40 °C
1.2: 70 percent / tetrahydrofuran / 0.75 h / -40 - -15 °C
View Scheme
参考文献
Stoll, Armin H.; Krasovskiy, Arkady; Knochel, Paul
Angewandte Chemie - International Edition, 2006 , vol. 45, # 4 p. 606 - 609
参考文献
Stoll, Armin H.; Krasovskiy, Arkady; Knochel, Paul
Angewandte Chemie - International Edition, 2006 , vol. 45, # 4 p. 606 - 609
反应条件
in tetrahydrofuran; water
T=50°C; 48 h;
参考文献
Aggarwal, Varinder K.; De Vicente, Javier; Pelotier, Beatrice; Holmes, Ian P.; Bonnert, Roger V.
Tetrahedron Letters, 2000 , vol. 41, # 52 p. 10327 - 10331
反应条件
1.1: Mg / tetrahydrofuran / Heating
1.2: 36 percent / tetrahydrofuran / 1.67 h / 0 - 20 °C
2.1: 52 percent / K2Cr2O7; H2SO4; acetic acid / H2O; toluene / 19 h / 20 °C
View Scheme
参考文献
Blakemore, Paul R.; Marsden, Stephen P.; Vater, Huw D.
Organic Letters, 2006 , vol. 8, # 4 p. 773 - 776
反应条件
1.1: Mg / tetrahydrofuran / Heating
1.2: 36 percent / tetrahydrofuran / 1.67 h / 0 - 20 °C
2.1: 52 percent / K2Cr2O7; H2SO4; acetic acid / H2O; toluene / 19 h / 20 °C
View Scheme
参考文献
Blakemore, Paul R.; Marsden, Stephen P.; Vater, Huw D.
Organic Letters, 2006 , vol. 8, # 4 p. 773 - 776
反应条件
bicyclolt;2.2.2gt;octane-2,3-dione
10 h; Irradiation;
参考文献
Rubin, Mordecai B.; Gutman, Arie L.
Journal of Organic Chemistry, 1986 , vol. 51, # 13 p. 2511 - 2515
参考文献
Tiffeneau; Kuriaki
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1939 , vol. 209, p. 465
反应条件
1: 1) lithium diisopropylamide / 1) THF, -70 deg C, 20 min, 2) THF, -70 deg C, 10 min
2: 86 percent / 30percent aq. KOH / methanol / 1 h / Ambient temperature
3: 90 percent / sodium benzeneselenolate / ethanol / 2 h / 60 °C
View Scheme
参考文献
Satoh, Tsuyoshi; Kaneko, Youhei; Izawa, Takao; Sakata, Kiichi; Yamakawa, Koji
Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 7 p. 1983 - 1990
反应条件
1: 1) lithium diisopropylamide / 1) THF, -70 deg C, 20 min, 2) THF, -70 deg C, 10 min
2: 86 percent / 30percent aq. KOH / methanol / 1 h / Ambient temperature
3: 90 percent / sodium benzeneselenolate / ethanol / 2 h / 60 °C
View Scheme
参考文献
Satoh, Tsuyoshi; Kaneko, Youhei; Izawa, Takao; Sakata, Kiichi; Yamakawa, Koji
Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 7 p. 1983 - 1990
反应条件
1: 86 percent / 30percent aq. KOH / methanol / 1 h / Ambient temperature
2: 90 percent / sodium benzeneselenolate / ethanol / 2 h / 60 °C
View Scheme
参考文献
Satoh, Tsuyoshi; Kaneko, Youhei; Izawa, Takao; Sakata, Kiichi; Yamakawa, Koji
Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 7 p. 1983 - 1990
