in neat (no solvent)
byproducts: N2, ClCH2CO2CH2CH3; 1 equiv of diazoester adding slowly to an equimolar mixt. of Ge and Sn deriv. to result in an exothermic reaction with N2 evolution; allowing to stand for 24 h at 20°C; analyzed by gas chromy. and NMR spectroscopy;
参考文献
Castel, A.; Riviere, P.; Satge, J.
Journal of Organometallic Chemistry, 1982 , vol. 232, # 2 p. 137 - 146
in neat (no solvent)
byproducts: N2, ClCH2CO2CH2CH3; 1 equiv of diazoester adding slowly to an equimolar mixt. of Ge and Sn deriv. to result in an exothermic reaction with N2 evolution; allowing to stand for 2 h at 20°C; analyzed by gas chromy. and NMR spectroscopy;
参考文献
Castel, A.; Riviere, P.; Satge, J.
Journal of Organometallic Chemistry, 1982 , vol. 232, # 2 p. 137 - 146
Bartrum, Hannah E.; Blakemore, David C.; Moody, Christopher J.; Hayes, Christopher J.
Journal of Organic Chemistry, 2010 , vol. 75, # 24 p. 8674 - 8676
