2,3,4,9-四氢-2-甲基-1H-咔唑合成路线 （共 12 条）
反应条件
hydrogen; palladium on activated charcoal in methanol
T=20°C; P=760 Torr; 2 h;
参考文献
Scott, Tricia L.; Burke, Nicholas; Carrero-Martinez, Grissell; Soederberg, Bjoern C.G.
Tetrahedron, 2007 , vol. 63, # 5 p. 1183 - 1190
反应条件
1,4-diaza-bicyclo[2.2.2]octane; palladium diacetate in N,N-dimethyl-formamide
T=105°C;
参考文献
Chen; Lieberman; Larsen; Verhoeven; Reider
Journal of Organic Chemistry, 1997 , vol. 62, # 9 p. 2676 - 2677
反应条件
phosphorus trichoride in benzene
0.5 h; Ambient temperature;
参考文献
Chakrabarty, Manas; Batabyal, Archana
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1992 , vol. 31, # 3 p. 199 - 201
反应条件
1: 75 percent / triphenylarsine; copper(I) iodide / bis(benzonitrile)palladium dichloride / 1-methyl-pyrrolidin-2-one / 48 h / 80 °C
2: 93 percent / hydrogen / palladium on carbon / methanol / 2 h / 20 °C / 760 Torr
View Scheme
参考文献
Scott, Tricia L.; Burke, Nicholas; Carrero-Martinez, Grissell; Soederberg, Bjoern C.G.
Tetrahedron, 2007 , vol. 63, # 5 p. 1183 - 1190
反应条件
1: 75 percent / triphenylarsine; copper(I) iodide / bis(benzonitrile)palladium dichloride / 1-methyl-pyrrolidin-2-one / 48 h / 80 °C
2: 93 percent / hydrogen / palladium on carbon / methanol / 2 h / 20 °C / 760 Torr
View Scheme
参考文献
Scott, Tricia L.; Burke, Nicholas; Carrero-Martinez, Grissell; Soederberg, Bjoern C.G.
Tetrahedron, 2007 , vol. 63, # 5 p. 1183 - 1190
反应条件
in acetic acid
2 h; Heating;
参考文献
Stoermer, Doris; Heathcock, Clayton H.
Journal of Organic Chemistry, 1993 , vol. 58, # 3 p. 564 - 568
参考文献
Borsche
Justus Liebigs Annalen der Chemie, 1908 , vol. 359, p. 76
反应条件
T=40.9°C; Rate constant;
参考文献
McLean et al.
Journal of the Chemical Society, 1955 , p. 2519
参考文献
Grammaticakis
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1939 , vol. 209, p. 317
Bulletin de la Societe Chimique de France, 1947 , p. 438,444
参考文献
Grammaticakis
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1939 , vol. 209, p. 317
Bulletin de la Societe Chimique de France, 1947 , p. 438,444
