phosphoric acid; water in water
reaction of a soln. of H3PO2 and Ag-phosphate in aq. H3PO4 at ambient temp. or on heating on a water bath; react. of Ag(1+) with H2PO2(1-) forming Ag, H2PO4(1-) and H(1+);;
methyltrioxorhenium (VII) in water
Kinetics; 0.1 M CF3SO3H, 25°C; treatment of CH3ReO3 with H3PO2 (UV-monitoring), then addn. of HClO4; not isolated, reaction followed by UV/VIS spectroscopy;
参考文献
Abu-Omar, Mahdi M.; Appelman, Evan H.; Espenson, James H.
Inorganic Chemistry, 1996 , vol. 35, # 26 p. 7751 - 7757
Rose, H.
Annalen der Physik (Weinheim, Germany), 1827 , vol. 9, p. 361 - 386
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Wurtz, A.
Liebigs Annalen der Chemie, 1842 , vol. 43, p. 318 - 334
phosphoric acid; water in water
reaction of a soln. of H3PO2 and Ag-phosphate in aq. H3PO4 at ambient temp. or on heating on a water bath; react. of Ag(1+) with H2PO2(1-) forming Ag, H2PO4(1-) and H(1+);;
参考文献
Sieverts, A.
Z. Anorg. Chem., 1909 , vol. 64, p. 29 - 64
