4-甲基-1-(1,1,1-三氯甲基)丁-2-烯基乙酸酯合成路线 （共 10 条）
反应条件
1: zinc; acetic acid; diethyl ether 2: copper-powder / Erhitzen des Reaktionsprodukts mit Essigsaeure und wss. HCl View Scheme
参考文献
Farkas et al.
Collection of Czechoslovak Chemical Communications, 1959 , vol. 24, p. 2230,2235
反应条件
acetic acid; zinc in diethyl ether 3 h; Heating;
参考文献
Zhdankina, G. M.; Kryshtal', G. V.; Serebryakov, E. P.; Yanovskaya, L. A.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1988 , vol. 37, # 12 p. 2589 - 2591
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1988 , # 12 p. 2868 - 2870
参考文献
Farkas et al.
Collection of Czechoslovak Chemical Communications, 1959 , vol. 24, p. 2230,2235
反应条件
pyridine; acetic anhydride in hexane
参考文献
FMC Corporation
Patent: US4022672 A1, 1977 ;
参考文献
Muljiani; Gadre; Modak; Pathan; Mitra
Tetrahedron Asymmetry, 1991 , vol. 2, # 4 p. 239 - 242
反应条件
sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride
1 h; Ambient temperature;
参考文献
Kryshtal', G. V.; Bogdanov, V. S.; Yanovskaya, L. A.; Volkov, Yu. P.; Trusova, E. I.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1981 , vol. 30, # 12 p. 2351 - 2354
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1981 , # 12 p. 2820 - 2823
反应条件
sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride in dichloromethane
3 h; Ambient temperature;
参考文献
Kryshtal', G. V.; Bogdanov, V. S.; Yanovskaya, L. A.; Volkov, Yu. P.; Trusova, E. I.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1981 , vol. 30, # 12 p. 2351 - 2354
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1981 , # 12 p. 2820 - 2823
反应条件
1: sodium tetrahydroborate / methanol / 1.17 h / 38 - 60 °C
2: triethylamine / 1.3 h / 95 °C
View Scheme
参考文献
Fishman, Ayelet; Kellner, Dorit; Ioffe, David; Shapiro, Evgeny
Organic Process Research and Development, 2000 , vol. 4, # 2 p. 77 - 87
反应条件
lipase from Pseudomonas fluorescens in aq. phosphate buffer
T=30°C; pH=7; 24 h; Enzymatic reaction; Reagent/catalyst; enantioselective reaction;
参考文献
Fishman, Ayelet; Kellner, Dorit; Ioffe, David; Shapiro, Evgeny
Organic Process Research and Development, 2000 , vol. 4, # 2 p. 77 - 87
反应条件
1: zinc; acetic acid; diethyl ether
2: copper-powder / Erhitzen des Reaktionsprodukts mit Essigsaeure und wss. HCl
3: SOCl2; hexane / Behandeln des Reaktionsprodukts mit (+-)-2-Allyl-4-hydroxy-3-methyl-cyclopent-2-enon in Benzol und Pyridin
View Scheme
参考文献
Farkas et al.
Collection of Czechoslovak Chemical Communications, 1959 , vol. 24, p. 2230,2235
