1-(三甲基硅氧烷)环己烯合成路线 （共 370 条）
反应条件
bismuth(III) chloride; sodium iodide in dichloromethane
5 h; Ambient temperature; Yields of byproduct given;
参考文献
Peidro, Laurence; Le Roux, Christophe; Laporterie, Andre; Dubac, Jacques
Journal of Organometallic Chemistry, 1996 , vol. 521, # 1-2 p. 397 - 399
反应条件
XeF2 in dichloromethane
var. solv. and material of vessel; Mechanism;
参考文献
Ramsden; Smith
Journal of the American Chemical Society, 1998 , vol. 120, # 27 p. 6842 - 6843
反应条件
in dichloromethane
18 h;
参考文献
Lerouge, Patrice; Paulmier, Claude
Bulletin de la Societe Chimique de France, 1985 , # 6 p. 1219 - 1224
反应条件
chloramine-T
1.) CH2Cl2, -12 deg C, 2.) CH2Cl2, -25 deg C, 30 min; Yield given. Multistep reaction;
参考文献
Magnus, Philip; Rigollier, Pascal
Tetrahedron Letters, 1992 , vol. 33, # 41 p. 6111 - 6114
参考文献
Ryu,I. et al.
Synthesis, 1977 , p. 874 - 876
反应条件
1.1: o-iodoxybenzoic acid (IBX); 4-methoxypyridine N-oxide / dimethylsulfoxide; CH2Cl2 / 1 h / 25 °C
2.1: CuBr*SMe2 / tetrahydrofuran / 0.5 h / -78 °C
2.2: N,N,N',N'-tetramethylethylenediamine / tetrahydrofuran / 0.5 h / -78 - 25 °C
3.1: o-iodoxybenzoic acid / dimethylsulfoxide / 20 °C
View Scheme
参考文献
Nicolaou; Gray, David L. F.; Montagnon, Tamsyn; Harrison, Scott T.
Angewandte Chemie - International Edition, 2002 , vol. 41, # 6 p. 996 - 1000
反应条件
(S)-difluoroPhos; AgOTf; cesium fluoride in tetrahydrofuran; methanol
T=-78°C; optical yield given as percent ee;
参考文献
Kawasaki, Masanori; Li, Pingfan; Yamamoto, Hisashi
Angewandte Chemie - International Edition, 2008 , vol. 47, # 20 p. 3795 - 3797
反应条件
titanium tetrachloride in dichloromethane
T=-50°C; 1.5 h;
参考文献
Reetz, Manfred T.; Maier, Wilhelm F.; Chatziiosifidis, Ioannis; Giannis, Athanassios; Heimbach, Horst; Loewe, Ursula
Chemische Berichte, 1980 , vol. 113, # 12 p. 3741 - 3757
反应条件
in dichloromethane
1 h, -70 deg C; 3 h, room temp.;
参考文献
Wanner Th.; Eiden
1984 , vol. 1984, # 6 p. 1100 - 1108
反应条件
1: 80 percent / Bu2Sn(OTf)2 / CH2Cl2 / 2 h / -50 °C
2: 91 percent / NaOMe / methanol / 0.5 h / Ambient temperature
View Scheme
参考文献
Sato, Tsuneo; Wakahara, Yoshiyuki; Otera, Junzo; Nozaki, Hitosi
Tetrahedron, 1991 , vol. 47, # 47 p. 9773 - 9782
