2,5-二甲基-1-己烯合成路线 （共 22 条）
反应条件
1: (i) Br2, hexane, Py, (ii) KOH, EtOH 2: KOtBu View Scheme
参考文献
Wolinsky,J. et al.
Journal of Organic Chemistry, 1976 , vol. 41, p. 745 - 750
参考文献
Salkind; Smagina
Zhurnal Obshchei Khimii, vol. 7, p. 473
Chem. Zentralbl., 1937 , vol. 108, # I p. 4490
反应条件
potassium permanganate; acetone
参考文献
Salkind; Smagina
Zhurnal Obshchei Khimii, vol. 7, p. 474
Chem. Zentralbl., 1937 , vol. 108, # I p. 4490
参考文献
Salkind; Smagina
Zhurnal Obshchei Khimii, vol. 7, p. 473
Chem. Zentralbl., 1937 , vol. 108, # I p. 4490
反应条件
sodium tetrahydroborate; Fe pythalocyanine; dimethylsulfide; oxygen in ethanol T=20°C; P=760.051 Torr;
参考文献
Angewandte Chemie - International Edition, , vol. 53, # 10 p. 2730 - 2734
Angew. Chem., , vol. 126, # 10 p. 2768 - 2772,5
反应条件
1: T=20°C; P=3863.02 Torr; Molecular sieve;
2: With nitrobenzene; tetrachloro-.pi.-diisobutylene dipalladium(II)
48 h; Inert atmosphere;
参考文献
GEVO, INC.; PETERS, Matthew W.; TAYLOR, Joshua D.; JENNI, Madeline; MANZER, Leo E.; HENTON, David E.
Patent: WO2011/44243 A1, 2011 ;
Location in patent: Page/Page column 42 ;
反应条件
1: tert-butyl hyponitrite, triethylamine / dimethyl ether / 1 h / -78 °C
2: hexane / -10 °C / other solvents, temperatures; Ea, log A, ΔH<*>, ΔS<*>, ET, ΔG<*>
View Scheme
参考文献
Hinsberg, William D.; Schultz, Peter G.; Dervan, Peter B.
Journal of the American Chemical Society, 1982 , vol. 104, # 3 p. 766 - 773
反应条件
1: 34 percent / lithium aluminium hydride / diethyl ether; dibutyl ether / 4 h / Heating
2: tert-butyl hyponitrite, triethylamine / dimethyl ether / 1 h / -78 °C
3: hexane / -10 °C / other solvents, temperatures; Ea, log A, ΔH<*>, ΔS<*>, ET, ΔG<*>
View Scheme
参考文献
Hinsberg, William D.; Schultz, Peter G.; Dervan, Peter B.
Journal of the American Chemical Society, 1982 , vol. 104, # 3 p. 766 - 773
反应条件
1: 90 percent / sodium nitrite / H2O / 72 h / 85 °C
2: 34 percent / lithium aluminium hydride / diethyl ether; dibutyl ether / 4 h / Heating
3: tert-butyl hyponitrite, triethylamine / dimethyl ether / 1 h / -78 °C
4: hexane / -10 °C / other solvents, temperatures; Ea, log A, ΔH<*>, ΔS<*>, ET, ΔG<*>
View Scheme
参考文献
Hinsberg, William D.; Schultz, Peter G.; Dervan, Peter B.
Journal of the American Chemical Society, 1982 , vol. 104, # 3 p. 766 - 773
反应条件
1: 1.) NaNO2, 2.) lithium alumunium hydride
2: tert-butyl hypochlorite, triethylamine / diethyl ether / -78 °C
3: diethyl ether / 0 °C
View Scheme
参考文献
Schultz, Peter G.; Dervan, Peter B.
Journal of the American Chemical Society, 1980 , vol. 102, # 2 p. 878 - 880
