(S)-(+)-2-壬醇合成路线 (共 34 条)
反应条件
[Ru(II)(η6-benzene)(μ-Cl)Cl]2; mono(3-deoxy-3-[N-methylamino])-β-CD; sodium formate in water; N,N-dimethyl-formamide T=25°C; 12 h; optical yield given as percent eeenantioselective reaction;
参考文献
Schlatter, Alain; Woggon, Wolf-D.
Advanced Synthesis and Catalysis, 2008 , vol. 350, # 7-8 p. 995 - 1000
反应条件
titanium(IV) isopropylate; zinc(II) chloride in toluene T=-78 - -30°C;
参考文献
Omote, Masaaki; Tanaka, Naoya; Tarui, Atsushi; Sato, Kazuyuki; Kumadaki, Itsumaro; Ando, Akira
Tetrahedron Letters, 2007 , vol. 48, # 17 p. 2989 - 2991
反应条件
1: dimethyl zinc With (R)-1,1'-bi-2-naphthol-based rigid regular chiral polymer in toluene Substitution; 0.166667 h; 2: Caprylic Aldehyde in toluene T=0°C; Addition; 72 h; Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 64, # 21 p. 7940 - 7956
参考文献
Journal of the Indian Chemical Society, , vol. 74, # 11-12 p. 937 - 939
反应条件
sprouted Pisum sativa in water T=25°C; 72 h; optical yield given as percent eeenantioselective reaction;
参考文献
Yadav, Jhillu S.; Subba Reddy, Basi V.; Sreelakshmi, Chittamuru; Rao, Adari Bhaskar
Synthesis, 2009 , # 11 art. no. Z01109SS, p. 1881 - 1885
反应条件
Escherichia coli BioH in hexane T=35°C; 28 h; Resolution of racemate; optical yield given as percent eeenantioselective reaction;
参考文献
Tetrahedron Letters, , vol. 51, # 48 p. 6360 - 6364
参考文献
Tetrahedron: Asymmetry, , vol. 3, # 9 p. 1149 - 1152
反应条件
1: 1M NaOH / lipase from Pseudomonas cepacia (SAM-I) 2: Raney-Nickel / methanol View Scheme
参考文献
Tetrahedron: Asymmetry, , vol. 3, # 9 p. 1149 - 1152
反应条件
Candida antarctica lipase B immobilized on acrylic resin catalyst in pentane T=20 - 25°C; 48 h; Enzymatic reaction; optical yield given as percent eeenantioselective reaction;
参考文献
Strohalm, Hedwig; Dold, Susanne; Pendzialek, Kathrin; Weiher, Monika; Engel, Karl-Heinz
Journal of Agricultural and Food Chemistry, 2010 , vol. 58, # 10 p. 6328 - 6333
反应条件
Candida antarctica lipase B immobilized on acrylic resin catalyst in pentane T=20 - 25°C; 48 h; Enzymatic reaction; optical yield given as percent eeenantioselective reaction;
参考文献
Strohalm, Hedwig; Dold, Susanne; Pendzialek, Kathrin; Weiher, Monika; Engel, Karl-Heinz
Journal of Agricultural and Food Chemistry, 2010 , vol. 58, # 10 p. 6328 - 6333