in methanol High Pressure; Co salt and phosphine dissolving in MeOH in a molar ratio 1:2, stirringfor 2 h under 80 bar of CO/H2 mixt. (1:1) at 225°C; not isolated, identified by IR spectrum;
in water Kinetics; soln. prepn. just before expt. by dissolving requisite amts. Co(NH2SO3)2in distd. deoxygenated H2O; then soln. put to cell, sparged with Ar for 30 min; detd. by NMR;
参考文献
Journal of the Electrochemical Society, , vol. 147, # 11 p. 4156 - 4163
