in gas byproducts: H2; total static pressure ca. 2E-7 Torr; Fourier transform mass spectrometry; branching ratio NbFe(C7H8)(1+)/Nb(C7H8)(1+) 31/69;
参考文献
Journal of Physical Chemistry, , vol. 93, # 9 p. 3667 - 3673
→
反应条件
in gas byproducts: H2; total static pressure ca. 2E-7 Torr; Fourier transform mass spectrometry; branching ratio NbFe(tropylium)2(1+)/Nb(tol)2(1+) 31/69;
参考文献
Journal of Physical Chemistry, , vol. 93, # 9 p. 3667 - 3673
in 1,3,5-trimethyl-benzene byproducts: CO; Ar atmosphere, heating (boiling); isomer mixt. (4-3''-η4/3'-4'η4 82:18) not separated, total yield 49percent; elem. anal.;
参考文献
Chemische Berichte, , vol. 121, p. 597 - 616
→
反应条件
in neat (no solvent) pelletizing of mixt. of Fe(CO)5, S and Ta; transferring to ampoules; evacuating, sealing, heating to 1273 K for 20 ds;
参考文献
Russian Journal of Inorganic Chemistry, , vol. 52, # 9 p. 1459 - 1463
Bulletin de la Societe Chimique de France, , vol. 25, # 2 p. 283
Chem. News J. Ind. Sci., , vol. 20, p. 55
Al: MVol.B1, 2.4.3, page 52 - 53
FR106229 , ;
EP8382 , ;
→
反应条件
in gas byproducts: H2; total static pressure ca. 2E-7 Torr; Fourier transform mass spectrometry; branching ratio NbFe(C10H10)(1+)/Nb(C10H11)81+)/Nb(C10H10)(1+) 5/65/30;
参考文献
Journal of Physical Chemistry, , vol. 93, # 9 p. 3667 - 3673
