反应条件
in toluene
byproducts: NaBr, N2, NH3; High Pressure; (inert atm.); heating mixt. of nickel bromide, NaN3 and toluene to 100°C at 11°C/h, keeping for 3 h, heating to 120°C at 5°C, keeping for 17 h, heating at 170°C for 4 h, heating to 270°C for 4 d, keeping for 1 d; isolation of ppt., drying in vac., washing with methanol, drying in vac., powder XRD, elem. anal. and EDS;
参考文献
Choi, Jonglak; Gillan, Edward G.
Inorganic Chemistry, 2009 , vol. 48, # 10 p. 4470 - 4477
