in neat (no solvent, solid phase)
using Schlenk techniques; heating to 500°C for 1 h in quartz tube, cooling to room temp. under Ar flow; monitoring by XRD;
参考文献
Knisley, Thomas J.; Saly, Mark J.; Heeg, Mary Jane; Roberts, John L.; Winter, Charles H.
Organometallics, 2011 , vol. 30, # 18 p. 5010 - 5017
in neat (no solvent, solid phase)
in TGA app.; heating at rate 30°C/min to 600°C with first intermediate formation at 30-200°C and second intermediate formation at approx. 360°C;
参考文献
Rujiwatra, Apinpus; Yimklan, Saranphong; Prior, Timothy J.
Polyhedron, 2012 , vol. 31, # 1 p. 345 - 351
in acetonitrile-D3
T=-50 - 20°C; 12 h; GloveboxSchlenk techniqueInert atmosphere;
参考文献
Zheng, Bo; Tang, Fengzhi; Luo, Jia; Schultz, Jason W.; Rath, Nigam P.; Mirica, Liviu M.
Journal of the American Chemical Society, 2014 , vol. 136, # 17 p. 6499 - 6504
in ethylene glycol
heating soln. of carbonic acid, mixing with soln. of Ni-salt (heated to 185°C, pptn.); filtration, dispersing (EtOH), filtration, drying (vac., room temp.);
参考文献
Degen; Macek; Novosel
Journal of thermal analysis, 1997 , vol. 48, # 3 p. 657 - 664
