in water Dissoln. of Ni wire in aq. HCl at about 50°C using a piece of Pt in contact with the Ni (acting as cathode for better soln. of Ni).; Placement of NiCl2 in a quartz boat, vaporisation by heating to about 600°C, seeding of vapor in about 4 atm of Ar, expanding through nozzle (250μm hole).;
参考文献
Beattle, Ian R.; Spicer, Mark D.; Young, Nigel A.
Journal of Chemical Physics, 1994 , vol. 100, # 12 p. 8700 - 8705
in neat (no solvent, solid phase) mixt. of metal (tenfold excess) and AgCl heated in Ar (400 Torr) until react. was complete; cooled, evacuated, co-condensed with solid matrix (N2 or Ar);
参考文献
Beattie, Ian R.; Jones, Peter J.; Young, Nigel A.
Chemical Physics Letters, 1991 , vol. 177, p. 579 - 584
in gaseous matrix Defluorination in N2 atmosphere (flow rate 4l/h) at 560 °C/760 Torr.;
参考文献
Burdon, J.; Gilman, D. J.; Patrick, C. R.; Stacey, M.; Tatlow, J. C.
Nature (London, United Kingdom), 1960 , vol. 186, p. 231 - 232
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Gmelin Handbook: F: PerFHalOrg.5, 4, page 115 - 148
