triphenylphosphine in not given cocondensation of Ni with solvent (2 h, liquid N2 temp.), warming (77 K), reacting with excess of org. compd. (slightly above 77 K), warming (room temp.);
参考文献
Fisher, Keith J.; Alyea, Elmer C.
Polyhedron, 1989 , vol. 8, p. 13 - 16
Skell, P. S.; Havel, J. J.; Williams-Smith, D. L.; McGlichey, M. J.
Journal of the Chemical Society, Chemical Communications, 1972 , p. 1098 - 1099
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Gmelin Handbook: Ni: Org.Verb.2, 1.4.2.1.1, page 87 - 88
sodium methylate in methanol pyrophoric Ni under water layer added to a methanol soln. containing an equivalent quantity of phthalonitrile and 5 drops of 30percent soln of CH3ONa in methanol; flask maintained at 25°C for 24-72 h; blue product separated from unreacted metal by shaking and decanting with the solvent, washed with ethanol in Soxhlet equipment and dried in air; purity of 95-97percent; elem. anal.;
参考文献
Kharisov; Coronado, C.E. Cantu; Cerda, K.P. Coronado; Mendez, U. Ortiz; Guzman, J.A. Jacobo; Patlan, L.A. Ramirez
Inorganic Chemistry Communications, 2004 , vol. 7, # 12 p. 1269 - 1272
