in neat (no solvent) Electrolysis; crumbling of V-anode;; leakage of VCl4;;
参考文献
Marino, L.
Gazzetta Chimica Italiana, 1904 , vol. 34, # I p. 230 - 247
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Marino, L.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1904 , vol. 39, p. 152 - 169
in neat (no solvent) Electrolysis; crumbling of V-anode;; leakage of VCl4;;
参考文献
Marino, L.
Gazzetta Chimica Italiana, 1904 , vol. 34, # I p. 230 - 247
Full Text Show Details
Marino, L.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1904 , vol. 39, p. 152 - 169
in neat (no solvent) byproducts: S2, CO; react. of V-powder with streaming SOCl2 and COCl2 at 600 to 700°C;; gaseous VCl4 besides gaseous S2 and CO obtained;;
参考文献
Gmelin Handbook: V: MVol.A2, 81, page 519 - 521
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Meyer, J.; Backa, R.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1924 , vol. 135, p. 177 - 193
oxygen in neat (no solvent) react. of V powder with gaseous Cl2 in presence of O2 at ambient temp., faster on heating;; VCl4 contaminated with VOCl3 obtained;;
